The 100 most-cited articles in RSC Advances, 2024

The photocatalytic field revolves around the utilization of photon energy to initiate various chemical reactions using non-adsorbing substrates, through processes such as single electron transfer, energy transfer, or atom transfer. The efficiency of this field depends on the capacity of a light-absorbing metal complex, organic molecule, or substance (commonly referred to as photocatalysts or PCs) to execute these processes. Photoredox techniques utilize photocatalysts, which possess the essential characteristic of functioning as both an oxidizing and a reducing agent upon activation. In addition, it is commonly observed that photocatalysts exhibit optimal performance when irradiated with low-energy light sources, while still retaining their catalytic activity under ambient temperatures. The implementation of photoredox catalysis has resuscitated an array of synthesis realms, including but not limited to radical chemistry and photochemistry, ultimately affording prospects for the development of the reactions. Also, photoredox catalysis is utilized to resolve numerous challenges…

The intriguing optoelectronic properties, diverse applications, and facile fabrication techniques of perovskite materials have garnered substantial research interest worldwide. Their outstanding performance in solar cell applications and excellent efficiency at the lab scale have already been proven. However, owing to their low stability, the widespread manufacturing of perovskite solar cells (PSCs) for commercialization is still far off. Several instability factors of PSCs, including the intrinsic and extrinsic instability of perovskite materials, have already been identified, and a variety of approaches have been adopted to improve the material quality, stability, and efficiency of PSCs. In this review, we have comprehensively presented the significance of band gap tuning in achieving both high-performance and high-stability PSCs in the presence of various degradation factors. By investigating the mechanisms of band gap engineering, we have highlighted its pivotal role in optimizing PSCs for improved efficiency and resilience.

Perovskite solar cells (PSCs) have emerged as revolutionary technology in the field of photovoltaics, offering a promising avenue for efficient and cost-effective solar energy conversion. This review provides a comprehensive overview of the progress and developments in PSCs, beginning with an introduction to their fundamental properties and significance. Herein, we discuss the various types of PSCs, including lead-based, tin-based, mixed Sn-Pb, germanium-based, and polymer-based PSCs, highlighting their unique attributes and performance metrics. Special emphasis is given to halide double PSCs and their potential in enhancing the stability of PSCs. Charge transport layers and their significance in influencing the overall efficiency of solar cells are discussed in detail. The review also explores the role of tandem solar cells as a solution to overcome the limitations of single-junction solar cells, offering an integrated approach to harness a broader spectrum of sunlight. This review concludes with challenges associated with PSCs and perspective on the future potential of PSCs,…

In comparison to rechargeable batteries, supercapacitors have advantages such as quick charging and high power density. This review is focused on the progress in the development of electrode materials for supercapacitors using composite materials based on conducting polymers, graphene, metal oxide nanoparticles/nanofibres, and CNTs. Moreover, we investigated different types of ESDs as well as their electrochemical energy storage mechanisms and kinetic aspects. We have also discussed the classification of different types of SCs; advantages and drawbacks of SCs and other ESDs; and the use of nanofibres, carbon, CNTs, graphene, metal oxide-nanofibres, and conducting polymers as electrode materials for SCs. Furthermore, modifications in the development of different types of SCs such as pseudo-capacitors, hybrid capacitors, and electrical double-layer capacitors are discussed in detail; both electrolyte-based and electrolyte-free supercapacitors are taken into consideration. This review will help in designing and fabricating high-performance supercapacitors with high energy density and…

Water scarcity will worsen due to population growth, urbanization, and climate change. Addressing this issue requires developing energy-efficient and cost-effective water purification technologies. One approach is to use biomass to make bio-based materials (BBMs) with valuable attributes. This aligns with the goal of environmental conservation and waste management. Furthermore, the use of biomass is advantageous because it is readily available, economical, and has minimal secondary environmental impact. Biomass materials are ideal for water purification because they are abundant and contain important functional groups like hydroxyl, carboxyl, and amino groups. Functional groups are important for modifying and absorbing contaminants in water. Single-sourced biomass has limitations such as weak mechanical strength, limited adsorption capacity, and chemical instability. Investing in research and development is crucial for the development of efficient methods to produce BBMs and establish suitable water purification application models. This review covers BBM production, modification,…

Effective corrosion control strategies are highly desired to reduce the fate of corrosion. One widely adopted approach is the use of corrosion inhibitors, which can significantly mitigate the detrimental effects of corrosion. This systematic review provides a thorough analysis of corrosion inhibitors, including both inorganic and organic compounds. It explores the inhibition mechanisms, highlighting the remarkable inhibitive efficiency of organic compounds attributed to the presence of heteroatoms and conjugated π-electron systems. The review presents case studies and investigations of corrosion inhibitors, shedding light on their performance and application potential. Moreover, it compares the efficacy, compatibility, and sustainability of emerging environmentally friendly corrosion inhibitors, including biopolymers from natural resources as promising candidates. The review also highlights the potential of synergistic impacts between mixed corrosion inhibitors, particularly organic/organic systems, as a viable and advantageous choice for applications in challenging processing…

Water is a fundamental resource, yet various contaminants increasingly threaten its quality, necessitating effective remediation strategies. Sustainable polymeric adsorbents have emerged as promising materials in adsorption-based water remediation technologies, particularly for the removal of contaminants and deactivation of water-borne pathogens. Pathogenetic water contamination, which involves the presence of harmful bacteria, viruses, and other microorganisms, poses a significant threat to public health. This review aims to analyze the unique properties of various polymeric materials, including porous aromatic frameworks, biopolymers, and molecularly imprinted polymers, and their effectiveness in water remediation applications. Key findings reveal that these adsorbents demonstrate high surface areas, tunable surface chemistries, and mechanical stability, which enhance their performance in removing contaminants such as heavy metals, organic pollutants, and emerging contaminants from water sources. Furthermore, the review identifies gaps in current research and suggests future…

One such technology is hydrogen-based which utilizes hydrogen to generate energy without emission of greenhouse gases. The advantage of such technology is the fact that the only by-product is water. Efficient storage is crucial for the practical application of hydrogen. There are several techniques to store hydrogen, each with certain advantages and disadvantages. In gaseous hydrogen storage, hydrogen gas is compressed and stored at high pressures, requiring robust and expensive pressure vessels. In liquid hydrogen storage, hydrogen is cooled to extremely low temperatures and stored as a liquid, which is energy-intensive. Researchers are exploring advanced materials for hydrogen storage, including metal hydrides, carbon-based materials, metal-organic frameworks (MOFs), and nanomaterials. These materials aim to enhance storage capacity, kinetics, and safety. The hydrogen economy envisions hydrogen as a clean energy carrier, utilized in various sectors like transportation, industry, and power generation. It can contribute to decarbonizing sectors that are challenging to electrify…

Graphitic carbon nitride (g-C 3 N 4 )-based materials have emerged as promising photocatalysts due to their unique band structure, excellent stability, and environmental friendliness.

Recently, metal-organic frameworks (MOFs) have attracted much attention as versatile materials for drug delivery and personalized medicine. MOFs are porous structures made up of metal ions coupled with organic ligands. This review highlights the synthesis techniques used to design MOFs with specific features such as surface area and pore size, and the drug encapsulation within MOFs not only improves their stability and solubility but also allows for controlled release kinetics, which improves therapeutic efficacy and minimizes adverse effects. Furthermore, it discusses the challenges and potential advantages of MOF-based drug delivery, such as MOF stability, biocompatibility, and scale-up production. With further advancements in MOF synthesis, functionalization techniques, and understanding of their interactions using biological systems, MOFs can have significant promise for expanding the area of personalized medicine and improving patient outcomes.

capture materials, offering economic advantages and supporting sustainable waste management.

The prevention and treatment of microbial infections is an imminent global public health concern due to the poor antimicrobial performance of the existing antimicrobial regime and rapidly emerging antibiotic resistance in pathogenic microbes. In order to overcome these problems and effectively control bacterial infections, various new treatment modalities have been identified. To attempt this, various micro- and macro-molecular antimicrobial agents that function by microbial membrane disruption have been developed with improved antimicrobial activity and lesser resistance. Antimicrobial nanoparticle-hydrogels systems comprising antimicrobial agents (antibiotics, biological extracts, and antimicrobial peptides) loaded nanoparticles or antimicrobial nanoparticles (metal or metal oxide) constitute an important class of biomaterials for the prevention and treatment of infections. Hydrogels that incorporate nanoparticles can offer an effective strategy for delivering antimicrobial agents (or nanoparticles) in a controlled, sustained, and targeted manner. In this review, we have described…

This paper presents a comprehensive review of recent advancements in utilizing zinc oxide nanoparticles (ZnO NPs) to enhance antimicrobial and UV protective properties in healthcare solutions. It delves into the synthesis techniques of ZnO NPs and elucidates their antimicrobial efficacy, exploring the underlying mechanisms governing their action against a spectrum of pathogens. Factors impacting the antimicrobial performance of ZnO NPs, including size, surface characteristics, and environmental variables, are extensively analyzed. Moreover, recent studies showcasing the effectiveness of ZnO NPs against diverse pathogens are critically examined, underscoring their potential utility in combatting microbial infections. The study further investigates the UV protective capabilities of ZnO NPs, elucidating the mechanisms by which they offer UV protection and reviewing recent innovations in leveraging them for UV-blocking applications in healthcare. It also dissects the factors influencing the UV shielding performance of ZnO NPs, such as particle size, dispersion quality, and surface…

Global concerns about food security, driven by rising demand, have prompted the exploration of nanotechnology as a solution to enhance food supply. This shift comes in response to the limitations of conventional technologies in meeting the ever-increasing demand for food products. Consequently, nanoparticles play a crucial role in enhancing food production, preservation, and extending shelf life by imparting exceptional properties to materials. Nanoparticles and nanostructures with attributes like expansive surface area and antimicrobial efficacy, are versatile in both traditional packaging and integration into biopolymer matrices. These distinctive qualities contribute to their extensive use in various food sector applications. Hence, this review explores the physicochemical properties, functions, and biological aspects of nanoparticles in the context of food packaging. Furthermore, the synergistic effect of nanoparticles with different biopolymers, alongside its different potential applications such as food shelf-life extenders, antimicrobial agents and as nanomaterials for…

Enzymes are widely used in biofuels, food, and pharmaceuticals. The immobilization of enzymes on solid supports, particularly magnetic nanomaterials, enhances their stability and catalytic activity. Magnetic nanomaterials are chosen for their versatility, large surface area, and superparamagnetic properties, which allow for easy separation and reuse in industrial processes. Researchers focus on the synthesis of appropriate nanomaterials tailored for specific purposes. Immobilization protocols are predefined and adapted to both enzymes and support requirements for optimal efficiency. This review provides a detailed exploration of the application of magnetic nanomaterials in enzyme immobilization protocols. It covers methods, challenges, advantages, and future perspectives, starting with general aspects of magnetic nanomaterials, their synthesis, and applications as matrices for solid enzyme stabilization. The discussion then delves into existing enzymatic immobilization methods on magnetic nanomaterials, highlighting advantages, challenges, and potential applications. Further…

were discussed. Moreover, the synthesis techniques, ranging from bottom-up to top-down methods are scrutinized for their efficacy in tailoring MAX phase properties. Furthermore, the review explores the challenges and opportunities associated with optimizing MAX phase materials for specific applications, such as enhancing their oxidation resistance, tuning their mechanical properties, and exploring their functionality in emerging technologies. Overall, this review aims to provide researchers and engineers with a comprehensive understanding of MAX phase materials and inspire further exploration into their versatile applications in materials science and engineering.

Fe) is provided. In addition, the limitations in the electrochemical characterization of intermetallic compounds, the research gap, and prospects are also provided in addition to the phenomenon of galvanic polarity reversal and self-dissolution of IMPs.

. Herein, we provide information on the role of the homogeneity and heterogeneity of adsorbents, kinetics of the adsorption of an adsorbate on the surface of an adsorbent, insights into adsorption reaction pathways, the mechanism of the sorption process, and the uptake of solutes from solution. The present review will be useful for researchers working on environmental protection and clean environment.

The surge in interest surrounding energy storage solutions, driven by the demand for electric vehicles and the global energy crisis, has spotlighted the effectiveness of carbon-based supercapacitors in meeting high-power requirements. Concurrently, metal-organic frameworks (MOFs) have gained attention as a template for their integration with graphene oxide (GO) in composite materials which have emerged as a promising avenue for developing high-power supercapacitors, elevating smart supercapacitor efficiency, cyclic stability, and durability, providing crucial insights for overcoming contemporary energy storage obstacles. The identified combination leverages the strengths of both materials, showcasing significant potential for advancing energy storage technologies in a sustainable and efficient manner. In this research, an in-depth review has been presented, in which properties, rationale and integration of MOF/GO composites have been critically examined. Various fabrication techniques have been thoroughly analyzed, emphasizing the specific attributes of MOFs, such as high surface…

This review explores the ever-evolving landscape of thermoelectric materials, focusing on the latest trends and innovations in ceramics, thermally conductive gel-like materials, metals, nanoparticles, polymers, and silicon. Thermoelectric materials have garnered significant attention for their capability to convert waste heat into electrical power, positioning them as promising candidates for energy harvesting and cooling applications. This review distinguishes itself by highlighting recent advancements in synthesis methods, advanced doping strategies, and nanostructuring techniques that have markedly enhanced material performance. It provides a comprehensive analysis of the controlled properties concerning their synthesis parameters, such as electrical conductivity, Seebeck coefficient, and thermal conductivity. Furthermore, this work delves into the emerging applications of thermoelectric devices across diverse fields, including automotive, aerospace, wearable electronics, and industrial waste heat recovery. By offering forward-looking insights, this review outlines thermoelectric…

surface repulsion and anti-adhesion properties, and enhanced structural stability, are discussed. Furthermore, the review provides a critical analysis of the challenges and limitations associated with the use of nanomaterials to modify RO membranes. Overall, this review provides valuable insights into the modification of RO membranes with nanomaterials, providing a full grasp of the benefits, challenges, and future prospects of this challenging topic.

Carbon composites derived from Metal-Organic Frameworks (MOFs) have shown great promise as multipurpose materials for a range of electrochemical and environmental applications. Since carbon-based nanomaterials exhibit intriguing features, they have been widely exploited as catalysts or catalysts supports in the chemical industry or for energy or environmental applications. To improve the catalytic performance of carbon-based materials, high surface areas, variable porosity, and functionalization are thought to be essential. This study offers a thorough summary of the most recent developments in MOF-derived carbon composite synthesis techniques, emphasizing innovative approaches that improve the structural and functional characteristics of the materials. Their uses in electrochemical technologies, such as energy conversion and storage, and their function in environmental electrocatalysis for water splitting and pollutant degradation are also included in the debate. This review seeks to clarify the revolutionary effect of carbon composites formed from MOFs on sustainable technology…

different approaches, such as luminescence, electrochemical, colorimetric, and surface-enhanced Raman spectroscopic techniques, is also discussed. The high porosity and chemical tunability of MOFs are the main driving forces for their widespread applications, which have huge potential for their commercial use.

, metal organic frameworks (MOFs), layered double hydroxides (LDHs), and carbon quantum dots (CQDs)-based composites, exhibit remarkable performance. The future of synergistic photocatalysis envisions large-scale production facilitate integrating advanced 2D and 3D semiconductor photocatalysts, presenting a promising avenue for sustainable and efficient pollutant degradation and hydrogen production from environmental remediation technologies.

H low-field Nuclear Magnetic Resonance (NMR) and Isothermal Conduction Calorimetry (ISC), and others and phenomenological models such as the John-Mehl-Avrami-Kolmogorov (JMAK) model, modified Jandar model, and exponential and Knudson linear dispersion models were used to study the geopolymerization kinetics and many mechanisms were proposed for the synthesis of geopolymers. The mechanistic tools and phenomenological models provided new insights about geopolymerization kinetics and formation mechanisms but each of the techniques used possesses some limitations. These limitations need to be removed and new methods or techniques must be developed to overcome these challenges and get more detailed information about all types of geopolymers. The formation mechanism consists of three to four stages such as dissolution of raw materials, polymerization of silica and alumina, condensation, and reorganization. The Si/Al ratio above the Si/Al ratio of reactants is more suitable and it increases the rate or degree of reaction and produces a higher compressive strength geopolymer. The Na/Al…

Spiro heterocycle frameworks are a class of organic compounds that possesses unique structural features making them highly sought-after targets in drug discovery due to their diverse biological and pharmacological activities. Microwave-assisted organic synthesis has emerged as a powerful tool for assembling complex molecular architectures. The use of microwave irradiation in synthetic chemistry is a promising method for accelerating reaction rates and improving yields. This review provides insights into the current state of the art and highlights the potential of microwave-assisted multicomponent reactions in the synthesis of novel spiro heterocyclic compounds that were reported between 2017 and 2023.

The growing apprehension surrounding heavy metal pollution in both environmental and industrial contexts has spurred extensive research into adsorption materials aimed at efficient remediation. Among these materials, Metal-Organic Frameworks (MOFs) have risen as versatile and promising contenders due to their adjustable properties, expansive surface areas, and sustainable characteristics, compared to traditional options like activated carbon and zeolites. This exhaustive review delves into the synthesis techniques, structural diversity, and adsorption capabilities of MOFs for the effective removal of heavy metals. The article explores the evolution of MOF design and fabrication methods, highlighting pivotal parameters influencing their adsorption performance, such as pore size, surface area, and the presence of functional groups. In this perspective review, a thorough analysis of various MOFs is presented, emphasizing the crucial role of ligands and metal nodes in adapting MOF properties for heavy metal removal. Moreover, the review delves into recent advancements in MOF-based…

Safe drinking water and a clean living environment are essential for good health. However, the extensive and growing use of hazardous chemicals, particularly carcinogenic dyes like methylene blue, methyl orange, rhodamine B, and malachite green, in both domestic and industrial settings, has led to a scarcity of potable water and environmental challenges. This trend poses a serious threat to human society, sustainable global development, and marine ecosystems. Consequently, researchers are exploring more advanced methods beyond traditional wastewater treatment to address the removal or degradation of these toxic dyes. Conventional approaches are often inadequate for effectively removing dyes from industrial wastewater. In this study, we investigated bimetallic metal-organic frameworks (BMOFs) as a solution to these limitations. BMOFs demonstrated outstanding dye removal and degradation capabilities due to their multifunctionality, water stability, large surface area, adjustable pore size, and recyclability. This review provides a comprehensive overview of research on dye removal from…

Graphene, the most fascinating 2D form of carbon with closely packed carbon atoms arranged in a layer, needs more attention in various fields. For its unique electrical, mechanical, and chemical properties with a large surface area, graphene has been in the limelight since its first report. Graphene has extraordinary properties, making it the most promising electrode component for applications in supercapacitors. However, the persistent re-stacking of carbon layers in graphene, caused by firm interlayer van der Waals attractions, significantly impairs the performance of supercapacitors. As a result, many strategies have been used to get around the aforementioned problems. The utilization of graphene-based nanomaterials has been implemented to surmount the aforementioned constraints and considerably enhance the performance of supercapacitors. This review highlights recent progress in graphene-based nanomaterials with metal oxide, sulfides, phosphides, nitrides, carbides, and conducting polymers, focusing on their synthetic approach, configurations, and electrochemical properties for…

/Ni. These findings of the proposed CIGS-based double heterojunction (DH) solar cells offer an innovative method for realization of high-efficiency solar cells that are more promising than the previously reported traditional designs.

in MB. This work improved our understanding of the mechanism for MB adsorption by modified biochar and provided practical and theoretical guidance for adsorbent preparation with high adsorption ability for dyes.

This review examines the escalating issue of plastic pollution, specifically highlighting the detrimental effects on the environment and human health caused by microplastics and nanoplastics. The extensive use of synthetic polymers such as polyethylene (PE), polyethylene terephthalate (PET), and polystyrene (PS) has raised significant environmental concerns because of their long-lasting and non-degradable characteristics. This review delves into the role of enzymatic and microbial strategies in breaking down these polymers, showcasing recent advancements in the field. The intricacies of enzymatic degradation are thoroughly examined, including the effectiveness of enzymes such as PETase and MHETase, as well as the contribution of microbial pathways in breaking down resilient polymers into more benign substances. The paper also discusses the impact of chemical composition on plastic degradation kinetics and emphasizes the need for an approach to managing the environmental impact of synthetic polymers. The review highlights the significance of comprehending the physical characteristics…

Climate change is causing a rise in the need to transition from fossil fuels to renewable and clean energy such as hydrogen as a sustainable energy source. The issue with hydrogen's practical storage, however, prevents it from being widely used as an energy source. Current solutions, such as liquefied and compressed hydrogen storage, are insufficient to meet the U.S. Department of Energy's (US DOE) extensive on-board application requirements. Thus, a backup strategy involving material-based storage is required. Metal organic frameworks (MOFs) belong to the category of crystalline porous materials that have seen rapid interest in the field of energy storage due to their large surface area, high pore volume, and modifiable structure. Therefore, advanced technologies employed in the construction of MOFs, such as solvothermal, mechanochemical, microwave assisted, and sonochemical methods are reviewed. Finally, this review discussed the selected factors and structural characteristics of MOFs, which affect the hydrogen capacity.

Chitosan, a biopolymer acquired from chitin, has emerged as a versatile and favorable material in the domain of tissue engineering and wound healing. Its biocompatibility, biodegradability, and antimicrobial characteristics make it a suitable candidate for these applications. In tissue engineering, chitosan-based formulations have garnered substantial attention as they have the ability to mimic the extracellular matrix, furnishing an optimal microenvironment for cell adhesion, proliferation, and differentiation. In the realm of wound healing, chitosan-based dressings have revealed exceptional characteristics. They maintain a moist wound environment, expedite wound closure, and prevent infections. These formulations provide controlled release mechanisms, assuring sustained delivery of bioactive molecules to the wound area. Chitosan's immunomodulatory properties have also been investigated to govern the inflammatory reaction during wound healing, fostering a balanced healing procedure. In summary, recent progress in chitosan-based formulations portrays a substantial stride in tissue…

The fast rise of organic and metallic pollution has brought significant risks to human health and the ecological environment. Consequently, the remediation of wastewater is in extremely urgent demand and has received increasing attention. Nanoscale zero valent iron (nZVI) possesses a high specific surface area and distinctive reactive interfaces, which offer plentiful active sites for the reduction, oxidation, and adsorption of contaminants. Given these abundant functionalities of nZVI, it has undergone significant and extensive studies on environmental remediation, linking to various mechanisms, such as reduction, oxidation, surface complexation, and coprecipitation, which have shown great promise for application in wastewater treatment. Among these functionalities of nZVI, reductivity is particularly important and widely adopted in dehalogenation, and reduction of nitrate, nitro compounds, and metal ions. The following review comprises a short survey of the most recent reports on the applications of nZVI based on its reductivity. It contains five sections, an introduction to the…

Nanoparticle (NP) drug delivery systems have shown promise in tumor therapy. However, limitations such as susceptibility to immune clearance and poor targeting in a complex intercellular environment still exist. Recently, cancer cell membrane-encapsulated nanoparticles (CCM-NPs) constructed using biomimetic nanotechnology have been developed to overcome these problems. Proteins on the membrane surface of cancer cells can provide a wide range of activities for CCM-NPs, including immune escape and homologous cell recognition properties. Meanwhile, the surface of the cancer cell membrane exhibits obvious antigen enrichment, so that CCM-NPs can transmit tumor-specific antigen, activate a downstream immune response, and produce an effective anti-tumor effect. In this review, we first provided an overview of the functions of cancer cell membranes and summarized the preparation techniques and characterization methods of CCM-NPs. Then, we focused on the application of CCM-NPs in tumor therapy. In addition, we summarized the functional modifications of cancer cell membranes and compiled the…

This review highlights the antioxidant potential of Schiff base ligands via the DPPH assay, focusing on structure, solvent effects, and how electron-donating groups enhance radical stabilization, suggesting their role as eco-friendly antioxidants.

, and as catalysts for organic degradation and catalytic cracking. This review highlights the significance of coal gangue classification according to its properties for the comprehensive utilization of gangue. Additionally, we briefly introduce and discuss suggestions for future directions of research and development in this area. Nevertheless, with regard to the environmental impact of secondary pollution and the efficiency of coal gangue utilization, there remain numerous obstacles that hinder future research. This review is expected to provide significant insights into the development of coal gangue utilization strategies, potentially facilitating the efficient and practical large-scale management of solid waste.

, thermo-mechanical and morphological, biodegradability, dampness retention attributes, and potential applications have been extensively reviewed and reported. Besides, this review encompasses the deterrents and conceivable outcomes connected to NFCs, alongside their environmental implications and monetary feasibility. Through a critical evaluation of the existing literature, this article provides a detailed summary of NFCs for real-time engineering applications. It also provides insights into sustainability practices through NFCs.

, aluminum-air (Al-air) batteries have become the focus of research. Al-air batteries offer significant advantages in terms of high energy and power density, which can be applied in electric vehicles; however, there are limitations in their design and aluminum corrosion is a main bottleneck. Herein, we aim to provide a detailed overview of Al-air batteries and their reaction mechanism and electrochemical characteristics. This review emphasizes each component/sub-component including the anode, electrolyte, and air cathode together with strategies to modify the electrolyte, air-cathode, and even anode for enhanced performance. The latest advancements focusing on the specific design of Al-air batteries and their rechargeability characteristics are discussed. Finally, the constraints and prospects of their use in mobility applications are also covered in depth. Thus, the present review may pave the way for researchers and developers working in energy storage solutions to look beyond lithium/sodium ion-based storage solutions.

Water pollution from industrial sources presents a significant environmental challenge due to the presence of recalcitrant organic contaminants. These pollutants threaten human health and necessitate effective remediation strategies. This article reviewed the synergistic application of adsorption and Fenton oxidation for water treatment. Adsorption, a common technique, concentrates pollutants onto a solid surface, but offers limited degradation. Fenton oxidation, an advanced oxidation process (AOP), utilizes hydroxyl radicals for efficient organic compound breakdown. When adsorption and Fenton oxidation combine, adsorption pre-concentrates pollutants, boosting Fenton oxidation effectiveness. This review delves into the mechanisms and advantages of this integrated approach, highlighting its potential for enhanced removal of organic contaminants. The discussion encompasses the mechanisms of Fenton oxidation and the synergistic effects it has with adsorption. Additionally, various support materials employed in this combined process are explored, including carbon-based supports…

Carbon fiber (CF) has high strength, high modulus, and excellent high-temperature resistance and chemical stability; therefore, it is used in diverse fields. However, due to the lack of active functional groups on the surface of CF and surface defects generated during the preparation of CF, the wettability of the fiber surface is poor, which seriously affects the interface performance between the fiber and a resin matrix. In recent years, extensive research has been conducted on the surface modification of CF. In this review, studies on the surface modification of CF are summarized, including the various methods utilized, such as dry modification, wet modification, and nanomodification, as well as their current application status. As interest in this material increases, high-performance CFs will likely play an important role in many fields in the future.

Advancements in asymmetric synthesis in recent years have led to considerable interest in the development of single enantiomers of chiral drug molecules for medicinal chemistry settings. In this review, we want to compile examples of chiral medicines approved by the FDA in the years 2022 and 2023 with an emphasis on their synthesis along with information on chiral induction as well as enantiomeric excess.

Electrostatic spinning as a technique for producing nanoscale fibers has recently attracted increasing attention due to its simplicity, versatility, and loadability. Nanofibers prepared by electrostatic spinning have been widely studied, especially in biomedical applications, because of their high specific surface area, high porosity, easy size control, and easy surface functionalization. Wound healing is a highly complex and dynamic process that is a crucial step in the body's healing process to recover from tissue injury or other forms of damage. Single-component nanofibers are more or less limited in terms of structural properties and do not fully satisfy various needs of the materials. This review aims to provide an in-depth analysis of the literature on the use of electrostatically spun nanofibers to promote wound healing, to overview the infinite possibilities for researchers to tap into their biomedical applications through functional composite modification of nanofibers for advanced and multifunctional materials, and to propose directions and perspectives for future research.

The transition from conventional polyurethane (PU) to non isocyanate polyurethane (NIPU) is driven mainly by safety concerns, environmental considerations, and sustainability issues associated with the current PU technology. NIPU has emerged as a promising alternative, addressing limitations related to traditional PU production. There has been increasing interest in bio-based NIPU aligning with the aspiration for green materials and processes. One important biomass resource for the development of bio-based NIPU is vegetable oil, an abundant, renewable, and relatively low cost feedstock. As such, this review aims to provide insight into the progression of NIPU derived from vegetable oils. This article highlights the synthetic and green approach to NIPU production, emphasizing the method involving the polyaddition reaction of cyclic carbonates and amines. The review includes case studies on vegetable oil-based NIPU and perspectives on their properties. Further, discussions on the potential applications and commercial importance of PU and NIPU are included. Finally, we offer…

This review covers recent advancements in the synthesis of graphene quantum dots (GQDs) and their properties. It highlights GQDs' applications in bioimaging for tumor visualization and MRI, as well as in various biosensing technologies.

In recent years, flexible conductive materials have attracted considerable attention for their potential use in flexible energy storage devices, touch panels, sensors, memristors, and other applications. The outstanding flexibility, electricity, and tunable mechanical properties of hydrogels make them ideal conductive materials for flexible electronic devices. Various synthetic strategies have been developed to produce conductive and environmentally friendly hydrogels for high-performance flexible electronics. In this review, we discuss the state-of-the-art applications of hydrogels in flexible electronics, such as energy storage, touch panels, memristor devices, and sensors like temperature, gas, humidity, chemical, strain, and textile sensors, and the latest synthesis methods of hydrogels. Describe the process of fabricating sensors as well. Finally, we discussed the challenges and future research avenues for flexible and portable electronic devices based on hydrogels.

This mini-review on doping and heterojunctions for catalysis applications provides a comprehensive overview of key aspects. Doping, when carried out adequately with a uniform distribution, creates a new energy level that significantly enhances charge transfer and light absorption. This new level alters the material's morphology and enhances intrinsic defects. For instance, ZnO, despite its exceptional band edge concerning oxygen reduction and water oxidation redox potentials, faces the issue of electron-hole recombination. However, forming a heterojunction can effectively aid charge transfer and prolong electron-hole relaxation without recombination. This is where the role of doping and heterojunctions becomes crucial. Additionally, incorporating noble metals with S- and Z-scheme heterojunctions offers a promising mechanism for charge transfer and visible light harvesting, further amplifying the catalytic properties.

, well-distributed pore size, and excellent degree of graphitization, which all facilitate the rapid diffusion of ions and enhance the accessibility of the electrolyte to the electrode surface. Hence, this study provides a promising route for utilizing waste biomass as a low-cost, sustainable electrode material for energy storage devices.

Advanced tools like 3D laser scanning, X-ray μCT, and optical fiber sensing now outperform traditional methods like HCP and resistivity tests, which often fail to detect chloride-induced corrosion accurately.

Terpyridine-based metal complexes have emerged as versatile and indispensable building blocks in the realm of modern chemistry, offering a plethora of applications spanning from materials science to catalysis and beyond. This comprehensive review article delves into the multifaceted world of terpyridine complexes, presenting an overview of their synthesis, structural diversity, and coordination chemistry principles. Focusing on their diverse functionalities, we explore their pivotal roles in catalysis, supramolecular chemistry, luminescent materials, and nanoscience. Furthermore, we highlight the burgeoning applications of terpyridine complexes in sustainable energy technologies, biomimetic systems, and medicinal chemistry, underscoring their remarkable adaptability to address pressing challenges in these fields. By elucidating the pivotal role of terpyridine complexes as versatile building blocks, this review provides valuable insights into their current state-of-the-art applications and future potential, thus inspiring continued innovation and exploration in this exciting area of…

-nitrophenol) dyes under sunlight exposure with photocatalytic degradation of 85.61%, 79.10%, and 89.95% respectively. Additionally, the nanoparticles displayed antimicrobial activity against Gram-positive and Gram-negative bacteria, and noteworthy antioxidant potential. The anti-inflammatory activity of the ZnO NPs, attributed to their ability to inhibit protein denaturation, was dose-dependent. Overall, our findings highlight the versatile properties of the greenly synthesized ZnO NPs, showcasing their potential in environmental remediation, and antimicrobial formulations, and as promising candidates for further exploration in the biomedical fields, including drug delivery and therapeutics.

Over the past decade, transition metal (TM)-based electrodes have shown intriguing physicochemical properties and widespread applications, especially in the field of supercapacitor energy storage owing to their diverse configurations, composition, porosity, and redox reactions. As one of the most intriguing research interests, the design of porous architectures in TM-based electrode materials has been demonstrated to facilitate ion/electron transport, modulate their electronic structure, diminish strain relaxation, and realize synergistic effects of multi-metals. Herein, the recent advances in porous TM-based electrodes are summarized, focusing on their typical synthesis strategies, including template-mediated assembly, thermal decomposition strategy, chemical deposition strategy, and host-guest hybridization strategy. Simultaneously, the corresponding conversion mechanism of each synthesis strategy are reviewed, and the merits and demerits of each strategy in building porous architectures are also discussed. Subsequently, TM-based electrode materials are categorized into TM oxides,…

. The response and recovery times were 5 s and 221 s, respectively. The reported good sensing performances indicate the potential application of Ca-doped ZnO as a sensor material for ammonia detection.

Recently, graphene and graphene-based nanomaterials have emerged as advanced carbon functional materials with specialized unique electronic, optical, mechanical, and chemical properties. These properties have made graphene an exceptional material for a wide range of promising applications in biological and non-biological fields. The present review illustrates the structural modifications of pristine graphene resulting in a wide variety of derivatives. The significance of substitutional doping with alkali-metals, alkaline earth metals, and III-VII group elements apart from the transition metals of the periodic table is discussed. The paper reviews various chemical and physical preparation routes of graphene, its derivatives and graphene-based nanocomposites at room and elevated temperatures in various solvents. The difficulty in dispersing it in water and organic solvents make it essential to functionalize graphene and its derivatives. Recent trends and advances are discussed at length. Controlled reduction reactions in the presence of various dopants leading to nanocomposites along…

Benefiting from the unique surface plasmon properties, plasmonic metal nanoparticles can convert light energy into chemical energy, which is considered as a potential technique for enhancing plasmon-induced semiconductor photocatalytic reactions. Due to the shortcomings of large bandgap and high carrier recombination rate of semiconductors, their applications are limited in the field of sustainable and clean energy sources. Different forms of plasmonic nanoparticles have been reported to improve the photocatalytic reactions of adjacent semiconductors, such as water splitting, carbon dioxide reduction, and organic pollutant degradation. Although there are various reports on plasmonic metal-semiconductor photocatalysis, the related mechanism and frontier progress still need to be further explored. This review provides a brief explanation of the four main mechanisms of plasmonic metal-semiconductor photocatalysis, namely, (i) enhanced local electromagnetic field, (ii) light scattering, (iii) plasmon-induced hot carrier injection and (iv) plasmon-induced resonance energy transfer; some…

In the present era, the increase in free radical species (FRs) and multidrug-resistant (MDR) bacteria represents a major worldwide concern for public health. Biofilm development and the overuse and misuse of antibiotics could lead to the adaptation of bacteria to antimicrobial agents. Consequently, finding novel multifunctional species with antibacterial, antioxidant, and antibiofilm properties has become crucial in the fight against challenging bacterial infections and chronic inflammatory conditions. Metal-organic frameworks (MOFs) with zinc and cobalt metal centers are widely utilized in biological and environmental remediation owing to their versatility. In this study, multifunctional Zn-MOFs and Co-MOFs were successfully synthesized with zinc and cobalt as metal centers and 4,6-diamino-2-pyrimidinethiol as an organic linker using a hydrothermal technique. Numerous characterization techniques were used to fully examine the MOF structure, functionality, chemical makeup, crystalline structure, surface appearance, thermal behavior, and magnetic characteristics; the techniques…

Green hydrogen, a versatile and sustainable energy carrier, has garnered increasing attention as a critical element in the global transition to a low-carbon economy. This review article comprehensively examines the production, applications, and potential of green hydrogen, accompanied by the challenges and future prospects associated with its widespread adoption. The production of green hydrogen is a central focus, due to its environmental benefits and distinctive characteristics. The article delves into the various techniques and technologies employed in green hydrogen production, emphasizing the need for cost reduction and increased scale for economic viability. Focusing particularly on applications, the review discusses the diverse sectors where green hydrogen demonstrates immense promise. Challenges and limitations are explored, including the intermittent nature of renewable energy sources, high production costs, and the need for extensive hydrogen infrastructure. The article also highlights the pressing need for innovation in electrolysis technology and materials, emphasizing…

The pursuit of efficient and sustainable energy storage solutions has fueled significant interest in the development of advanced materials for supercapacitors. Among these, two-dimensional (2D) materials undoubtingly have emerged as promising candidates due to their unique structural and electrochemical properties. To address the inherent challenges such as restacking, limited ion-accessibility, limited scalability, stability under operational conditions, and the intricate balance between surface area and conductivity that hinder the practical application of 2D materials, this article delves into innovative approaches and emerging strategies and prospects that aim to enhance their performance and durability. A systematic exploration of synthesis methods, structural characteristics, and electrochemical performance as supercapacitor electrodes of key 2D materials, including graphene, MXenes, transition metal dichalcogenides (TMDCs), black phosphorous and phosphorene and their composites has been discussed. The discussion will extend to recent breakthroughs and innovations, shedding…

, highlighting their strong adsorption onto the metal surface. Their adsorption process was in line with the Langmuir isotherm. Density Functional Theory (DFT) and Molecular Dynamics (MD) modeling have been utilized to examine and clarify the relationship between the inhibitor and carbon steel (C.S).

Here, we explore the structural and optical properties of Ag-doped ZnO nanoparticles. We looked at the photocatalytic activity for degrading Methylene Blue and the antibacterial effectiveness against bacterial strains, including Gram-negative Escherichia coli and Gram-positive Bacillus subtilis .

(1) The synthesis technologies, characteristics, and advantages of TiO 2 –biochar-based photocatalysts are introduced. (2) Strategies to enhance the activity of TiO 2 –biochar-based photocatalysts are proposed from three systematic aspects.

The growing threat of environmental pollution to global environmental health necessitates a focus on the search for sustainable wastewater remediation materials coupled with innovative remediation strategies. Nano and micro zero-valent iron materials have attracted substantial researchers' attention due to their distinct physiochemical properties. This review article delves into novel micro- and nano-zero valent iron (ZVI) materials, analysing their synthesis methods, and exploring their multifaceted potential as a powerful tool for environmental remediation. This analysis contributes to the ongoing search of effective solutions for environmental remediation. Synthesis techniques are analysed based on their efficacy, scalability, and environmental impact, providing insights into existing methodologies, current challenges, and future directions for optimisation. Factors influencing ZVI materials' physicochemical properties and multifunctional engineering applications, including their role in wastewater and soil remediation, are highlighted. Environmental concerns, pros and cons, and…

Perovskite materials have attracted significant attention as innovative and efficient X-ray detectors owing to their unique properties compared to traditional X-ray detectors. Herein, chronologically, we present an in-depth analysis of X-ray detection technologies employing organic-inorganic hybrids (OIHs), all-inorganic and lead-free perovskite material-based single crystals (SCs), thin/thick films and wafers. Particularly, this review systematically scrutinizes the advancement of the diverse synthesis methods, structural modifications, and device architectures exploited to enhance the radiation sensing performance. In addition, a critical analysis of the crucial factors affecting the performance of the devices is also provided. Our findings revealed that the improvement from single crystallization techniques dominated the film and wafer growth techniques. The probable reason for this is that SC-based devices display a lower trap density, higher resistivity, large carrier mobility and lifetime compared to film- and wafer-based devices. Ultimately, devices with SCs showed…

Antibiotic contamination has become a severe issue and a dangerous concern to the environment because of large release of antibiotic effluent into terrestrial and aquatic ecosystems. To try and solve these issues, a plethora of research on antibiotic withdrawal has been carried out. Recently photocatalysis has received tremendous attention due to its ability to remove antibiotics from aqueous solutions in a cost-effective and environmentally friendly manner with few drawbacks compared to traditional photocatalysts. Considerable attention has been focused on developing advanced visible light-driven photocatalysts in order to address these problems. This review provides an overview of recent developments in the field of photocatalytic degradation of antibiotics, including the doping of metals and non-metals into ultraviolet light-driven photocatalysts, the formation of new semiconductor photocatalysts, the advancement of heterojunction photocatalysts, and the building of surface plasmon resonance-enhanced photocatalytic systems.

at an OLR of 850 g COD/L per day, pH of 4.4, and at 8 h HRT. The integration of artificial intelligence (AI) tools, such as artificial neural networks and support vector machines has emerged as a novel approach for optimizing reactor performance and predicting outcomes. These AI models help in identifying key operational parameters and their optimal ranges, thus enhancing the efficiency and reliability of BHP processes. The review also draws attention to the importance of life cycle and techno-economic analyses in assessing the environmental impact and economic viability of BHP, addressing potential challenges like high operating costs and energy demands during scale-up. Future research should focus on developing more efficient and cost-effective BHP systems, integrating advanced AI techniques for real-time optimization, and conducting comprehensive LCA and TEA to ensure sustainable and economically viable biohydrogen production. By addressing these areas, BHP can become a key component of the transition to sustainable energy sources, contributing to the reduction of greenhouse gas…

Production of green hydrogen on a large scale can negatively impact freshwater resources. Therefore, using seawater as an electrolyte in electrolysis is a desirable alternative to reduce costs and freshwater reliance. However, there are limitations to this approach, primarily due to the catalyst involved in the oxygen evolution reaction (OER). In seawater, the OER features sluggish kinetics and complicated chemical reactions that compete. This review first introduces the benefits and challenges of direct seawater electrolysis and then summarises recent research into cost-effective and durable OER electrocatalysts. Different modification methods for nickel-based electrocatalysts are thoroughly reviewed, and promising electrocatalysts that the authors believe deserve further exploration have been highlighted.

> 0.960) models has major influence on the rate of the adsorption procedure. The binary adsorption test demonstrated higher efficacy of the synthesized adsorbent in the removal of malachite as compared to rhodamine. This study sheds light on the design of a cost-effective semi-natural polymeric composite for treating dye-polluted wastewaters, a major milestone toward environmental and ecological sustainability.

Silica nanoparticles (SiNPs) have emerged as a multipurpose solution with wide-ranging applications in various industries such as medicine, agriculture, construction, cosmetics, and food production. In 1961, Stöber introduced a ground-breaking sol-gel method for synthesizing SiNPs, which carried a new era of exploration both in academia and industry, uncovering numerous possibilities for these simple yet multifaceted particles. Inspite of numerous reported literature with wide applicability, the synthesis of these nanoparticles with the desired size and functionalities poses considerable challenges. Over time, researchers have strived to optimize the synthetic route, particularly by developing greener approaches that minimize environmental impact. By reducing hazardous chemicals, energy consumption, and waste generation, these greener synthesis methods have become an important focus in the field. This review aims to provide a comprehensive analysis of the various synthetic approaches available for different types of SiNPs. Starting from the Stöber' method, we analyze other methods…

Laminarin, a complicated polysaccharide originating from brown algae, has emerged as a compelling candidate in the domain of biomedical research. This enigmatic molecule, composed of glucose units associated with both β-1,3 and β-1,6 glycosidic bonds, possesses an array of remarkable characteristics that render it auspicious for multifaceted biomedical applications. This review investigates the comprehensive potential of laminarin in the biomedical domain, emphasizing its remarkable biocompatibility, low cytotoxicity, and cell proliferation support. Laminarin's immunomodulatory attributes position it as an encouraging contender in immunotherapy and the development of vaccines. Moreover, its anti-inflammatory and antioxidant characteristics provide a promising avenue for combatting conditions associated with oxidative stress. In particular, laminarin excels as a drug delivery vehicle owing to its exceptional encapsulation capabilities emerging from its porous framework. Integrating pH and redox responsiveness in laminarin-based drug delivery systems is poised to redefine targeted…

The waste management industry uses an increasing number of mathematical prediction models to accurately forecast the behavior of organic pollutants during catalytic degradation. With the increasing quantity of waste generated, these models are critical for reinforcing the efficiency of wastewater treatment strategies. The application of machine-learning techniques in recent years has notably improved predictive models for waste management, which are essential for mitigating the impact of toxic commercial waste on global water supply. Organic contaminants, dyes, pesticides, surfactants, petroleum by-products, and prescription drugs pose risks to human health. Because traditional techniques face challenges in ensuring water quality, modern strategies are vital. Machine learning has emerged as a valuable tool for predicting the photocatalytic degradation of medicinal drugs and dyes, providing a promising avenue for addressing urgent demands in removing organic pollutants from wastewater. This research investigates the synergistic application of photocatalysis and machine learning for…

Electrical stimulation (ES) has emerged as a powerful therapeutic modality for enhancing biological wound healing. This non-invasive technique utilizes low-level electrical currents to promote tissue regeneration and expedite the wound healing process. ES has been shown to accelerate wound closure, reduce inflammation, enhance angiogenesis, and modulate cell migration and proliferation through various mechanisms. The principle goal of wound management is the rapid recovery of the anatomical continuity of the skin, to prevent infections from the external environment and maintain homeostasis conditions inside. ES at the wound site is a compelling strategy for skin wound repair. Several ES applications are described in medical literature like AC, DC, and PC to improve cutaneous perfusion and accelerate wound healing. This review aimed to evaluate the primary factors and provides an overview of the potential benefits and mechanisms of ES in wound healing, and its ability to stimulate cellular responses, promote tissue regeneration, and improve overall healing outcomes. We also shed…

NiCoMn metal–organic frameworks (MOFs) are one of the most sought-after materials in the domain of supercapacitors. Here, they are composited with rGO and polyaniline to increase surface area and conductivity, aiming for enhanced energy density.

, β-lactamase), and membrane alterations that reduce the antibiotic's binding affinity and entry. Microbes also resist antimicrobials through peptidoglycan precursor modification, ribosomal subunit methylation, and alterations in metabolic enzymes. Rapid development of new strategies is essential to curb the spread of AMR and microbial infections. Nanomedicines, with their small size and unique physicochemical properties, offer a promising solution by overcoming drug resistance mechanisms such as reduced drug uptake, increased efflux, biofilm formation, and intracellular bacterial persistence. They enhance the therapeutic efficacy of antimicrobial agents, reduce toxicity, and tackle microbial resistance effectively. Various nanomaterials, including polymeric-based, lipid-based, metal nanoparticles, carbohydrate-derived, nucleic acid-based, and hydrogels, provide efficient solutions for AMR. This review addresses the epidemiology of microbial resistance, outlines key resistance mechanisms, and explores how nanomedicines overcome these barriers. In conclusion, nanomaterials represent…

electroporation of cell walls, thereby resulting in shorter processing times, lower energy inputs, greater retention of thermosensitive components, and higher extraction yields. In this regard, this review offers a comprehensive discussion on the innovative biorefinery strategies to the valorization of OPW, with a specific focus on recent studies assessing the technical feasibility of methodologies for the extraction of phytochemical compounds, dehydration processes, and bioconversion methods. Recent studies that discussed the potential of PEF technology to reduce energy demand by increasing the mass transfer of biological tissues were emphasized.

ions could be quickly, sensitively, and extremely selectively detected in an aqueous solution of carbon dots, with a revealing limit of 0.409 μM in the linear range of 0-180 μM. Interestingly, this recognition boundary is far inferior to the WHO-recommended threshold of 0.77 μM. Two metric tools which were AGREE and the ComplexGAPI were also used to evaluate the method's greenness. The evaluation confirmed its superior environmental friendliness.

The development of non-noble metal based and cost-effective electrocatalysts for water splitting has attracted significant attention due to their potential in production of clean and green hydrogen fuel. Discovered in 2011, a family of two-dimensional transition metal carbides, nitrides, and carbonitrides, have demonstrated promising performance as electro catalysts in the water splitting process due to their high electrical conductivity, very large surface area and abundant catalytic active sites. However, their-long term stability and recyclability are limited due to restacking and agglomeration of MXene flakes. This problem can be solved by combining MXene with other materials to create their hybrid architectures which have demonstrated higher electrocatalytic performance than pristine MXenes. Electrolysis of water encompasses two half-cell reactions, hydrogen evolution reaction (HER) at the cathode and oxygen evolution reaction (OER) at the anode. Firstly, this concise review explains the mechanism of water splitting. Then it provides an overview of the recent advances about…

This study explores the impact of fly ash (FA) filler on the mechanical, morphological, and water absorption properties of pineapple leaf fibre (PALF)-reinforced epoxy composites for biomedical applications. PALF, sourced from abundant agricultural waste, offers a sustainable alternative to synthetic fibres. Employing the hand layup process, varying wt% of FA (3%, 6%, and 9%) are incorporated into PALF-reinforced epoxy composites with different PALF concentrations (10%, 20%, and 30%). Mechanical assessments, including impact, flexural, and tensile strength, reveal that the introduction of up to 6 wt% FA enhances tensile strength by 65.3%, reaching its peak at this concentration. Flexural strength also improves by 31.9% with 6 wt% FA, while impact resistance reaches its maximum (74.18% improvement) at 9 wt% FA. Water absorption measurements demonstrate a decrease with increased FA content and exposure period, indicating enhanced water resistance. Scanning electron microscopy confirms the uniform distribution of FA, contributing to improved mechanical characteristics and water…

Proposed antibacterial mechanisms of Cu-BTC and Cu-GA. Both MOFs release Cu 2+ ions from their framework, facilitating their attachment and internalization on the surface of both E. coli (Gram-negative) and Lactobacillus (Gram-positive) bacteria.

) of VEGFR-2 inhibitors are discussed herein. The common structural framework requirements, such as the Asp-Phe-Gly (DFG) motif of VEGFR-2 interacting with the HBD-HBA region in the ligand molecules, the central aryl ring occupying the linker region, and a variety of bio-isosteres, can enhance activity against VEGFR-2. At one end, the heteroaryl moiety is essential for interaction within the ATP-binding site of VEGFR-2, while the terminal hydrophobic tail occupies the allosteric binding site. Three to five bond spacers between the heteroaryl and HBD-HBA regions provided a better result towards VEGFR-2 inhibition, mirroring the behaviors of standard drugs. The in-depth analysis of recent updates on VEGFR-2 inhibitors presented in this paper will help prospective synthetic and medicinal chemists to discover new lead molecules for the treatment of various cancers.

This work explores one centrosymmetric binuclear Cu( ii )-Salen complex synthesis, characterization, photosensitive Schottky barrier diode (PSBD) function, and DFT spectrum.

) in nature. These investigations suggested that the fabricated hydrogel membrane could be suitably used for methyl red adsorption from the solution.

(64%) for 30 minutes at 45 °C. The chemical and microstructure analysis showed that the lignin and hemicellulose contents of raw RH had been eliminated, and the crystallinity content of CNC was 67.16%. According to transmission electron microscopy (TEM) morphological analysis, CNC measured 19 ± 3.3 nm in diameter, 195 ± 24 nm in length, and 10.2 ± 6.8 in aspect ratio. The thermal stability of RH and CNC was also investigated using thermogravimetric analysis (TGA). These encouraging findings demonstrated the potential for reusing RH agricultural waste to create CNC and include nanocomposites as a reinforcing material.

to be established as a high-performance material for photovoltaic applications. Overall, our development contributes to the advancement of environmentally friendly solar technologies.

and Ag nanomaterials widened the catalytic activity spectrum from the visible region to the UV-region. Besides, these materials hindered the electron-hole recombination, boosting the catalytic activity. The reusability results also clearly showed that the synthesized ternary nanomaterials have good reproducibility and stability for photocatalytic degradation of industrial wastewater.

Gas sensing technology has a broad impact on society, ranging from environmental and industrial safety to healthcare and everyday applications, contributing to a safer, healthier, and more sustainable world.

Carbon nanomaterials have attracted significant attention in the biomedical field, including for biosensing, drug delivery, and tissue engineering applications. Based on their inherent properties such as their unique structure and high conductivity, carbon nanomaterials can overcome the current limitations in biomedical research such as poor stability of biomolecules, low sensitivity and selectivity of biosensors, and difficulty in precise drug delivery. In addition, recently, several novel nanomaterials have been integrated with carbon nanomaterials to develop carbon-based nanocomposites for application in biomedical research. In this review, we discuss recent studies on carbon-based nanocomposites and their biomedical applications. First, we discuss the representative carbon nanomaterials and nanocomposites composed of carbon and other novel nanomaterials. Next, applications of carbon nanomaterials and nanocomposites in the biomedical field are discussed according to topics in the biomedical field. We have discussed the recent studies on biosensors, drug delivery, and tissue…

) in the samples at 18 GHz. Both dielectric loss and conduction loss occurred because of the strong interactions involving polarization, charge propagation, and the creation of conductive routes through the incorporation of graphene in the polymer matrix. These properties/shielding results indicate the potential of the composites to be used as lightweight EM shielding materials. These materials are suitable shield materials for electronic devices to protect them from harmful electromagnetic radiation, making them vital in various applications.

Hydroxyapatite (HAp) is comparable to materials in bone because its chemical components are similar to those contained in animal bone, and thus, its bioactive and biocompatible properties are similar. There are applications for HAp and relevant calcium phosphate in the medical and industrial sectors, and due to the rising demand for HAp nanoparticles, considerable work has been performed to develop a variety of synthetic pathways that incorporate scientifically and practically novel aspects. Numerous studies have been conducted to examine how changes in reaction parameters will successfully influence crucial HAp features. HAp can also be synthesized from biogenic sources such as HAp-rich fish scales or animal bones as an alternative to chemical precursors. Various preparation techniques produce crystals with varying sizes, but it has been found that nano-sized HAp exhibits a greater number of bioactive properties as compared to micron-sized HAp. Rather than considering conventional methods, this review focuses on alternative approaches such as emulsion, pyrolysis, combustion, and…

Organic piezoelectric materials are emerging as integral components in the development of advanced implantable self-powered sensors for the next generation. Despite their promising applications, a key limitation lies in their reduced mechanical force-to-electricity conversion efficiency. In this study, we present a breakthrough in the fabrication of soft poly(vinylidene fluoride) (PVDF) organic electrospun piezoelectric nanofibers (OEPNs) with exceptional piezoelectric performance achieved through the incorporation of zinc oxide nanorods (ZnO NR). The inclusion of ZnO NR proved instrumental in augmenting the nanocrystallization of PVDF organic electrospun piezoelectric nanofibers (OEPNs), leading to a highly efficient crystal phase transformation from the α phase to the β/γ phase, serving as superior piezoelectric working dipoles. The resulting PVDF/ZnO NR OEPNs exhibited unparalleled piezoelectric output voltage and current density, particularly noteworthy under a micro-pressure of 1 kPa and a low frequency of 1.5 Hz. Utilizing the obtained PVDF/ZnO NR OEPNs as the piezoelectric…

Inspired by the captivating allure of exquisitely regulated characteristics exhibited by 2-(2-hydroxyphenyl)-benzoxazole and its derivatives in the realms of photochemistry and photophysics, our current endeavor primarily revolves around delving into the intricacies of photo-induced excited state reactions for derivatives of 2,5-bis(2-benzoxazolyl)-hydroquinone (BBHQ). Given the significant impact of chalcogen element doping, herein we predominantly focus on exploring the excited state behaviors of BBHQ-OO, BBHQ-SS, and BBHQ-SeSe fluorophores. Our simulations, resulting from variations in geometry and vertical excitation charge reorganization, reveal atomic-electronegativity-dependent hydrogen bonding interactions and charge recombination induced by photoexcitation that can significantly enhance the excited state intramolecular double proton transfer (ESDPT) reaction for BBHQ-OO, BBHQ-SS, and BBHQ-SeSe fluorophores. By constructing potential energy surfaces (PESs) and identifying transition states (TS), we unveil the ultrafast stepwise ESDPT mechanism due to the low potential…

Polymeric biomaterials are a widely used class of materials due to their versatile properties. However, as with all other types of materials used for biomaterials, polymers also have to interact with blood. When blood comes into contact with any foreign body, it initiates a cascade which leads to platelet activation and blood coagulation. The implant surface also has to encounter a thromboinflammatory response which makes the implant integrity vulnerable, this leads to blood coagulation on the implant and obstructs it from performing its function. Hence, the surface plays a pivotal role in the design and application of biomaterials. In particular, the surface properties of biomaterials are responsible for biocompatibility with biological systems and hemocompatibility. This review provides a report on recent advances in the field of surface modification approaches for improved hemocompatibility. We focus on the surface properties of polysaccharides, proteins, and synthetic polymers. The blood coagulation cascade has been discussed and blood - material surface interactions have also…

with hydrophobic(water insoluble) as well as hydrophilic(water soluble) properties) can modulate interfacial tension. Currently, the majority of surfactants depend on petrochemical feedstocks (such as oil and gas). However, deployment of these petrochemical surfactants produces high toxicity and also has poor biodegradability which can cause more environmental issues. To address these concerns, the current research is moving toward natural resources to produce sustainable surfactants. Among the available natural resources, Cashew Nut Shell Liquid (CNSL) is the preferred choice for industrial scenarios to meet their goals of sustainability. CNSL is an oil extracted from non-edible cashew nut shells, which doesn't affect the food supply chain. The unique structural properties and diverse range of use cases of CNSL are key to developing eco-friendly surfactants that replace petro-based surfactants. Against this backdrop, this article discusses various state-of-the-art developments in key cardanol-based surfactants such as anionic, cationic, non-ionic, and zwitterionic. In addition to…

Carbon monoxide, one of the major pollutants in the air, is mainly produced due to the incomplete combustion of fossil fuels such as coal and oil. Among all the techniques developed for removing CO, catalytic oxidation has been considered one of the most effective approaches, and the commonly used catalysts include metal oxides and noble metals. Noble metal attracted extensive attention due to its good catalytic performance at low temperatures and high resistance to poisoning. The review summarizes the recent advances of noble metals including Pt, Pd, Au, Ru, Rh, and Ir in CO oxidation. The effect of support, metal doping, the particle size of noble metals, and the hydroxyl groups on CO oxidation is discussed. Besides, the metal-support interaction on the stability and activity is also involved in this review. Finally, the challenges and opportunities of supported noble metal catalysts in practical CO oxidation are proposed.

results demonstrated that nanofiber mats containing SCLE and collagen significantly improved wound healing within two weeks, compared to the control untreated group. These findings highlight the potential of fabricated nanofibers in accelerating wound healing and management of topical acute wounds.

-methyl d-aspartate receptors, phosphodiesterase, amyloid β protein, protein phosphatase 2A, glycogen synthase kinase-3 beta, β-secretase, γ-secretase, α-secretase, serotonergic receptors, glutaminyl cyclase, tumor necrosis factor-α, γ-aminobutyric acid receptors, and mitochondria. All of these targets have been involved in the design of new potential drugs. An extensive number of these drugs have been studied in clinical trials. However, only galantamine, donepezil, and rivastigmine (ChEIs), memantine (NMDA antagonist), and aducanumab and lecanemab (selective anti-Aβ monoclonal antibodies) have been approved for AD treatment. Many drugs failed in the clinical trials to such an extent that questions have been posed about the significance of some of the aforementioned targets. On the contrary, the data of other drugs were promising and shed light on the significance of their targets for the development of new potent anti-alzheimer drugs.

-Ag microspheres into polymer matrices and investigating their surface characteristics represents a strategic step toward tailoring material properties for potential applications in active packaging and biomedicine.

. This work demonstrates the effect of different pore volumes on the electrocatalytic activity of AC derived from natural product waste. Our results indicate the feasibility of employing these electrodes for lab-scale applications. Thus, the AC material emerges as a highly promising substance, poised to advance the creation of cost-efficient, environmentally sustainable, high-performance, high-power devices.

Nonsteroidal anti-inflammatory drugs (NSAIDs) are the most abundantly used classes among therapeutic agents in medicine. NSAIDs inhibit the enzyme cyclooxygenase (COX), which is responsible for the conversion of arachidonic acid to prostaglandins. Meanwhile, non-selective NSAIDs are considered as a double-edged weapon since inhibition of COX-1 can lead to gastrointestinal side effects and kidney damage, whereas selective COX-2 inhibition provides anti-inflammatory effects without gastrointestinal toxicity. The detection of COX-2 role in inflammation process launched a new era in its management. Several trials have been established to proceed towards selectivity of well-defined anti-inflammatory members. COX-2 selective inhibitors are evidently safer on the gastrointestinal tract than non-selective NSAIDs. Nevertheless, their unexpected cardiovascular risks cannot be ignored. This review article highlights the latest trials aimed at developing new compounds with promising selective COX-2 activity.

The ongoing trend towards miniaturizing electronic devices and increasing their power densities has created substantial challenges in managing the heat they produce. Traditional heat sink designs often fall short of meeting modern electronics' rigorous thermal management needs. As a result, researchers and engineers are turning to innovative heat sink designs and optimization methods to improve thermal performance. This review article offers an overview of the latest advancements in designing and optimising advanced heat sinks for electronic cooling. It explores various techniques to enhance heat transfer, including advanced surface geometries and microchannels. Additionally, the review covers computational fluid dynamics (CFD) modelling and experimental validation methods used to refine heat sink designs. Further insight into fouling and its prevention has been discussed. The insights provided in this article are intended to serve as a valuable resource for thermal engineers, and researchers focused on managing the heat in high-power electronic systems.