The 100 most-cited articles in RSC Advances, 2021

is used to study them effectively. Here in this review we seek to describe the transport models which help to explain the conduction mechanism, relevant synthesis approaches, and physical properties, including electrical, optical and mechanical properties. Recent developments in their applications in the fields of energy storage, photocatalysis, anti-corrosion coatings, biomedical applications and sensing applications are also explained. Structural properties play an important role in the performance of the composites.

Electrochemical impedance spectroscopy (EIS) is a highly applicable electrochemical, analytical, and non-invasive technique for materials characterization, which allows the user to evaluate the impact, efficiency, and magnitude of different components within an electrical circuit at a higher resolution than other common electrochemical techniques such as cyclic voltammetry (CV) or chronoamperometry. EIS can be used to study mechanisms of surface reactions, evaluate kinetics and mass transport, and study the level of corrosion on conductive materials, just to name a few. Therefore, this review demonstrates the scope of physical properties of the materials that can be studied using EIS, such as for characterization of supercapacitors, dye-sensitized solar cells (DSSCs), conductive coatings, sensors, self-assembled monolayers (SAMs), and other materials. This guide was created to support beginner and intermediate level researchers in EIS studies to inspire a wider application of this technique for materials characterization. In this work, we provide a summary of the essential…

In spite of the fact that petroleum-based plastics are convenient in terms of fulfilling the performance requirements of many applications, they contribute significantly to a number of ecological and environmental problems. Recently, the public awareness of the negative effects of petroleum-based plastics on the environment has increased. The present utilization of natural resources cannot be sustained forever. Furthermore, oil is often subjected to price fluctuations and will eventually be depleted. The increase in the level of carbon dioxide due to the combustion of fossil fuel is causing global warming. Concerns about preservation of natural resources and climate change are considered worldwide motivations for academic and industrial researchers to reduce the consumption and dependence on fossil fuel. Therefore, bio-based polymers are moving towards becoming the favorable option to be utilized in polymer manufacturing, food packaging, and medical applications. This paper represents an overview of the feasibility of both Poly Lactic Acid (PLA) and polyhydroxyalkanoates (PHAs) as…

This review summarizes and elaborates the new findings in this research domain of the green synthesis of silver nanoparticles (AgNPs) using different plant extracts and their potential applications as antimicrobial agents covering the literature since 2015. While highlighting the recently used different plants for the synthesis of highly efficient antimicrobial green AgNPs, we aim to provide a systematic in-depth discussion on the possible influence of the phytochemicals and their concentrations in the plants extracts, extraction solvent, and extraction temperature, as well as reaction temperature, pH, reaction time, and concentration of precursor on the size, shape and stability of the produced AgNPs. Exhaustive details of the plausible mechanism of the interaction of AgNPs with the cell wall of microbes, leading to cell death, and high antimicrobial activities have also been elaborated. The shape and size-dependent antimicrobial activities of the biogenic AgNPs and the enhanced antimicrobial activities by synergetic interaction of AgNPs with known commercial antibiotic drugs have…

From its uses in ancient civilisations, copper has an established history as an antimicrobial agent. Extensive research has determined the efficacy and mechanism of copper's antimicrobial activity against microorganisms. The process is multifaceted with the main mechanism of bactericidal activity being the generation of reactive oxygen species (ROS), which irreversibly damages membranes. Copper ions released from surfaces lead to RNA degradation and membrane disruption of enveloped viruses. For fungi, the mechanism involves the physical deterioration of the membrane and copper ion influx. Due to variations in the experimental parameters, it is difficult to compare studies directly. In this review article, we outline the importance of the experimental conditions currently employed and how they bear little resemblance to real-world conditions. We endorse previous recommendations calling for an update to industrial standard tests.

facile surface modification are compared with standard T-25 cell culture plates for cell growth and proliferation, which shows that the proposed surface is an attractive choice for efficient cell culture.

/NiO nanocomposites were synthesized with sonication powers of 50 and 30 W, respectively. The agglomerated nanoparticles were obtained using different sonication powers, including 15, 30, and 50 W. The results showed that upon increasing the sonication power, the particle size decreased. After characterization, the optical, electrical, magnetic, and photocatalytic properties of the NC were studied. The nanocomposites showed an antiferromagnetic behavior. In this study, the photocatalytic degradations of two dyes, AR14 and AB92, were investigated in the presence of DBNO NC. Furthermore, the effects of the amount of photocatalyst, the concentration of the dye solution, the type of organic dye, and light irradiation on the photocatalytic activity of the nanocomposite were studied. The results showed that with an increasing amount of catalyst and decreasing concentration of dye, the photocatalytic activity of the nanocomposite was increased. This activity for the degradation of AR14 is higher than that of AB92. Both AR14 and AB92 dyes show higher photocatalytic degradation under UV…

non-renewable precursors, focusing on discrepancies in their physical, chemical, and optical properties. The development of cost effective, safe, and sustainable green CDs with tunable properties will broaden their implementation in largely untapped applications, which include drug delivery, photovoltaics, catalysis, and more.

Global warming is considered one of the world's leading challenges in the 21st century as it causes severe concerns such as climate change, extreme weather events, ocean warming, sea-level rise, declining Arctic sea ice, and acidification of oceans.

Nanostructured materials have gained immense attraction because of their extraordinary properties compared to the bulk materials to be used in a plethora of applications in myriad fields. In this review article, we have discussed how the Density Functional Theory (DFT) calculation can be used to explain some of the properties of nanomaterials. With some specific examples here, it has been shown that how closely the different properties of nanomaterials (such as optical, optoelectronics, catalytic and magnetic) predicted by DFT calculations match well with the experimentally determined values. Some examples were discussed in detail to inspire the experimental scientists to conduct DFT-based calculations along with the experiments to derive a better understanding of the experimentally obtained results as well as to predict the properties of the nanomaterial. We have pointed out the challenges associated with DFT, and potential future perspectives of this new exciting field.

There is increasing concern regarding alleviating world energy demand by determining an alternative to petroleum-derived fuels due to the rapid depletion of fossil fuels, rapid population growth, and urbanization. Biodiesel can be utilized as an alternative fuel to petroleum-derived diesel for the combustion engine. At present, edible crops are the primary source of biodiesel production. However, the excessive utilization of these edible crops for large-scale biodiesel production might cause food supply depletion and economic imbalance. Moreover, the utilization of edible oil as a biodiesel feedstock increases biodiesel production costs due to the high price of edible oils. A possible solution to overcome the existing limitations of biodiesel production is to utilize non-edible crops oil as a feedstock. The present study was conducted to determine the possibility and challenges of utilizing non-edible oil as a potential feedstock for biodiesel production. Several aspects related to non-edible oil as a biodiesel feedstock such as overview of biodiesel feedstocks, non-edible oil…

Wide usage of plastic products leads to the global occurrence of microplastics (MPs) in the aquatic environment. Due to the small size, they can be bio-ingested, which may cause certain health effects. The present review starts with summarizing the main sources of various types of MPs and their occurrences in the aquatic environment, as well as their transportation and degradation pathways. The analysis of migration of MPs in water environments shows that the ultimate fate of most MPs in water environments is cracked into small fragments and sinking into the bottom of the ocean. The advantages and disadvantages of existing methods for detection and analysis of MPs are summarized. In addition, based on recent researches, the present review discusses MPs as carriers of organic pollutants and microorganisms, and explores the specific effects of MPs on aquatic organisms in the case of single and combined pollutants. Finally, by analysing the causes and influencing factors of their trophic transfer, the impact of MPs on high-level trophic organisms is explored.

indicating the ability for a broad potential of energy and power related applications. To the best of our knowledge, these values are the highest ever reported for ionic liquid-based supercapacitors with activated carbon obtained from the biomass of coconut shells.

) fruits are extensively grown in tropical countries. The use of coconut husk-derived coir fiber-reinforced biocomposites is on the rise nowadays due to the constantly increasing demand for sustainable, renewable, biodegradable, and recyclable materials. Generally, the coconut husk and shells are disposed of as waste materials; however, they can be utilized as prominent raw materials for environment-friendly biocomposite production. Coir fibers are strong and stiff, which are prerequisites for coir fiber-reinforced biocomposite materials. However, as a bio-based material, the produced biocomposites have various performance characteristics because of the inhomogeneous coir material characteristics. Coir materials are reinforced with different thermoplastic, thermosetting, and cement-based materials to produce biocomposites. Coir fiber-reinforced composites provide superior mechanical, thermal, and physical properties, which make them outstanding materials as compared to synthetic fiber-reinforced composites. However, the mechanical performances of coconut fiber-reinforced composites…

Na) and their multifaceted synthetic applications. Substantial progress has been made over the last decade in the utilization of sodium sulfinates emerging as sulfonylating, sulfenylating or sulfinylating reagents, depending on reaction conditions. Sodium sulfinates act as versatile building blocks for preparing many valuable organosulfur compounds through S-S, N-S, and C-S bond-forming reactions. Remarkable advancement has been made in synthesizing thiosulfonates, sulfonamides, sulfides, and sulfones, including vinyl sulfones, allyl sulfones, and β-keto sulfones. The significant achievement of developing sulfonyl radical-triggered ring-closing sulfonylation and multicomponent reactions is also thoroughly discussed. Of note, the most promising site-selective C-H sulfonylation, photoredox catalytic transformations and electrochemical synthesis of sodium sulfinates are also demonstrated. Holistically, this review provides a unique and comprehensive overview of sodium sulfinates, which summarizes 355 core references up to March 2020. The chemistry of sodium sulfinate salts is divided…

Tyrosinase is a multifunctional glycosylated and copper-containing oxidase that is highly prevalent in plants and animals and plays a pivotal role in catalyzing the two key steps of melanogenesis: tyrosine's hydroxylation to dihydroxyphenylalanine (DOPA), and oxidation of the latter species to dopaquinone. Melanin guards against the destructive effects of ultraviolet radiation which is known to produce considerable pathological disorders such as skin cancer, among others. Moreover, the overproduction of melanin can create aesthetic problems along with serious disorders linked to hyperpigmented spots or patches on skin. Several skin-whitening products which reduce melanogenesis activity and alleviate hyperpigmentation are commercially available. A few of them, particularly those obtained from natural sources and that incorporate a phenolic scaffold, have been exploited in the cosmetic industry. In this context, synthetic tyrosinase inhibitors (TIs) with elevated efficacy and fewer side effects are direly needed in the pharmaceutical and cosmetic industries owing to their protective…

is the most favoured photocatalyst that is frequently used in photocatalytic water treatment. Dry-wet co-spinning and sputtering techniques emerged as the promising technique for immobilizing a uniformly distributed photocatalyst within the polymeric membrane, and exhibited excellence pollutant removal. In general, the technical applicability is the key factor in selecting the best photocatalyst immobilizing technique for water treatment. Finally, the scope of various techniques that have been reviewed may provide potential for future photocatalytic study.

Excessive levels of dyes and heavy metals in water sources have long been a source of concern, posing significant environmental and public health threats. However, adsorption is a feasible technique for removing dye contaminants and heavy metals from water due to its high efficiency, cost-effectiveness, and easy operation. Numerous researchers in batch studies extensively evaluated various adsorbents such as natural materials, and agriculture-derived and industrial wastes; however, large-scale application is still missing. Nanotechnology is a novel approach that has arisen as one of the most versatile and cost-effective ways for dye and heavy metal removal. Its promotion on large-scale applications to investigate technological, fiscal, and environmental aspects for wastewater decontamination is particularly important. This review critically reviews wastewater treatment techniques, emphasizing the adsorption process and highlighting the most effective parameters: solution pH, adsorbent dosage, adsorbent particle size, initial concentration, contact time, and temperature. In addition,…

, inducible nitric oxide synthase, tumor necrosis factor-α, nuclear factor κB, leukotrienes, and some interleukins. Literature studies reveal that a large number of pyrimidines exhibit potent anti-inflammatory effects. SARs of numerous pyrimidines have been discussed in detail. Several possible research guidelines and suggestions for the development of new pyrimidines as anti-inflammatory agents are also given. Detailed SAR analysis and prospects together provide clues for the synthesis of novel pyrimidine analogs possessing enhanced anti-inflammatory activities with minimum toxicity.

To date, various reports have shown that metallic gold bhasma at the nanoscale form was used as medicine as early as 2500 B.C. in India, China, and Egypt. Owing to their unique physicochemical, biological, and electronic properties, they have broad utilities in energy, environment, agriculture and more recently, the biomedical field. The biomedical domain has been used in drug delivery, imaging, diagnostics, therapeutics, and biosensing applications. In this review, we will discuss and highlight the increasing control over metal and metal oxide nanoparticle structures as smart nanomaterials utilized in the biomedical domain to advance the role of biosynthesized nanoparticles for improving human health through wide applications in the targeted drug delivery, controlled release drug delivery, wound dressing, tissue scaffolding, and medical implants. In addition, we have discussed concerns related to the role of these types of nanoparticles as an anti-viral agent by majorly highlighting the ways to combat the Severe Acute Respiratory Syndrome Coronavirus-2 (SARS-CoV-2) pandemic, along…

Metal phthalocyanines (MPcs) are an abundant class of small molecules comprising of a highly conjugated cyclic structure with a central chelated metal ion. Due to their remarkable chemical, mechanical, and thermal stability MPcs have become popular for a multitude of applications since their discovery in 1907. The potential for peripheral and axial functionalization affords structural tailoring to create bespoke MPc complexes for various next generation applications. Specifically, thin-films of MPcs have found promising utility in medical and electronic applications where the need to understand the relationship between chemical structure and the resulting thin-film properties is an important ongoing field. This review aims to compile the fundamental principles of small molecule thin-film formation by physical vapour deposition and solution processing focusing on the nucleation and growth of crystallites, thermodynamic and kinetic considerations, and effects of deposition parameters on MPc thin-films. Additionally, the structure-property relationship of MPc thin-films is examined by…

Piezoelectricity, a linear electromechanical coupling, is of great interest due to its extensive applications including energy harvesters, biomedical, sensors, and automobiles. A growing amount of research has been done to investigate the energy harvesting potential of this phenomenon. Traditional piezoelectric inorganics show high piezoelectric outputs but are often brittle, inflexible and may contain toxic compounds such as lead. On the other hand, biological piezoelectric materials are biodegradable, biocompatible, abundant, low in toxicity and are easy to fabricate. Thus, they are useful for many applications such as tissue engineering, biomedical and energy harvesting. This paper attempts to explain the basis of piezoelectricity in biological and non-biological materials and research involved in those materials as well as applications and limitations of each type of piezoelectric material.

by using various techniques with different limits of detection are also summarized. This review provides progressive trends in the development of heteroatom doped GQDs and their various applications.

method, post treatment method, and chemical vapor deposition. The fundamentally influencing mechanisms of various heteroatoms in electrochemical property and porous structure are summarized in detail. Furthermore, this review provides an updated summary about the applications of different heteroatom-doped OMC in supercapacitor, electrocatalysis, and ion battery during the last decade. Finally, the future challenges and research strategies for heteroatom-doped OMC are also proposed.

O, and ZnO, and with conducting polymers are extensively utilized in both acidic and basic media. Moreover, Pd-based materials, transition metal-based materials, as well as transition metal-based materials are also points of interest for researchers nowadays. This review article delivers a broad vision of the current progress of the EOR process concerning noble metals and transition metals-based materials.

Nanotechnology is an emerging field of science, engineering, and technology concerning the materials in nanoscale dimensions. Several materials are used in dentistry, which can be modified by applying nanotechnology. Nanotechnology has various applications in dentistry to achieve reliable treatment outcomes. The most common nanometals used in dental materials are gold, silver, copper oxide, magnesium oxide, iron oxide, cerium oxide, aluminum oxide, titanium dioxide, and zinc oxide (ZnO). ZnO nanoparticles (NPs), with their unparalleled properties such as high selectivity, enhanced cytotoxicity, biocompatibility, and easy synthesis as important materials were utilized in the field of dentistry. With this background, the present review aimed to discuss the current progress and gain an insight into applications of ZnO NPs in nanodentistry, including restorative, endodontic, implantology, periodontal, prosthodontics, and orthodontics fields.

The worldwide demand for additive manufacturing (AM) is increasing due to its ability to produce more challenging customized objects based on the process parameters for engineering applications. The processing of conventional materials by AM processes is a critically demanded research stream, which has generated a path-breaking scenario in the rapid manufacturing and upcycling of plastics. The exponential growth of AM in the worldwide polymer market is expected to exceed 20 billion US dollars by 2021 in areas of automotive, medical, aerospace, energy and customized consumer products. The development of functional polymers and composites by 3D printing-based technologies has been explored significantly due to its cost-effective, easier integration into customized geometries, higher efficacy, higher precision, freedom of material utilization as compared to traditional injection molding, and thermoforming techniques. Since polymers are the most explored class of materials in AM to overcome the limitations, this review describes the latest research conducted on petroleum-based polymers…

With rapid advancement in water filtration materials, several efforts have been made to fabricate electrospun nanofiber membranes (ENMs). ENMs play a crucial role in different areas of water treatment due to their several advantageous properties such as high specific surface area, high interconnected porosity, controllable thickness, mechanical robustness, and wettability. In the broad field of water purification, ENMs have shown tremendous potential in terms of permeability, rejection, energy efficiency, resistance to fouling, reusability and mechanical robustness as compared to the traditional phase inversion membranes. Upon various chemical and physical modifications of ENMs, they have exhibited great potential for emerging applications in environment, energy and health sectors. This review firstly presents an overview of the limiting factors influencing the morphology of electrospun nanofibers. Secondly, it presents recent advancements in electrospinning processes, which helps to not only overcome drawbacks associated with the conventional electrospinning but also to produce…

Recent advancement in nanotechnology has brought prominent benefits in tissue engineering, which has been used to repair or reconstruct damaged tissues or organs and design smart drug delivery systems. With numerous applications of nanomaterials in tissue engineering, it is vital to choose appropriate nanomaterials for different tissue engineering applications because of the tissue heterogeneity. Indeed, the use of nanomaterials in tissue engineering is directly determined by the choice. In this review, we mainly introduced the use of nanomaterials in tissue engineering. First, the basic characteristics, preparation and characterization methods of the types of nanomaterials are introduced briefly, followed by a detailed description of the application and research progress of nanomaterials in tissue engineering and drug delivery. Finally, the existing challenges and prospects for future applications of nanomaterials in tissue engineering are discussed.

have been summarized. Some of the basic properties, as well as synthesis techniques have also been outlined. This review will help the researcher to understand the properties and possible applications of tin selenide-based materials. Thus, this will help in advancing the field of tin selenide-based materials for next generation technology.

Ag–ZnO heterojunction promotes the separation of photogenerated pairs and thus exhibits high catalytic activity under UV-visible light.

Anthraquinones are privileged chemical scaffolds that have been used for centuries in various therapeutic applications. The anthraquinone moiety forms the core of various anticancer agents. However, the emergence of drug-resistant cancers warrants the development of new anticancer agents. The research endeavours towards new anthraquinone-based compounds are increasing rapidly in recent years. They are used as a core chemical template to achieve structural modifications, resulting in the development of new anthraquinone-based compounds as promising anticancer agents. Mechanistically, most of the anthraquinone-based compounds inhibit cancer progression by targeting essential cellular proteins. Herein, we review new anthraquinone analogues that have been developed in recent years as anticancer agents. This includes a systematic review of the recent literature (2005-2021) on anthraquinone-based compounds in cell-based models and key target proteins such as kinases, topoisomerases, telomerases, matrix metalloproteinases and G-quadruplexes involved in the viability of cancer cells. In…

Phase transformation from initially α-MnO 2 to R-MnO 2 due to Fe-doping cause modification of interatomic distances affects to the electrical properties.

The world has witnessed several incidents of epidemics and pandemics since the beginning of human existence. The gruesome effects of microbial threats create considerable repercussions on the healthcare systems. The continually evolving nature of causative viruses due to mutation or re-assortment sometimes makes existing medicines and vaccines inactive. As a rapid response to such outbreaks, much emphasis has been placed on personal protective equipment (PPE), especially face mask, to prevent infectious diseases from airborne pathogens. Wearing face masks in public reduce disease transmission and creates a sense of community solidarity in collectively fighting the pandemic. However, excessive use of single-use polymer-based face masks can pose a significant challenge to the environment and is increasingly evident in the ongoing COVID-19 pandemic. On the contrary, face masks with inherent antimicrobial properties can help in real-time deactivation of microorganisms enabling multiple-use and reduces secondary infections. Given the advantages, several efforts are made incorporating…

, room temperature, aqueous solutions, and the presence of mild bases. Undeniably, the Sonogashira reaction is among the most competent and efficient reactions widely used in organic synthesis. This named reaction has proved useful in many organic synthesis areas, including the synthesis of pharmaceuticals, heterocycles, natural products, organic compounds, complex molecules having biological activities, nanomaterials, and many more materials that we use in our daily lives. The presence of transition metals as a catalyst was indeed essential in the Sonogashira reaction. However, recently, the reaction has been successfully conducted without copper as a co-catalyst and phosphines or amines as bases. In this critical review, we have focused on developments in the Sonogashira reaction successfully performed in the absence of copper complexes, phosphines or amines, which could be of particular advantage in implementing green chemistry principles and making the reactions more achievable from an economic viewpoint.

One of the important aims in the synthesis of zeolite imidazolate framework-8 is to prepare crystals with predictable structures and valuable properties. It is observed that the properties of ZIF-8 have been directly or indirectly determined by various synthetic factors. Among many synthetic factors, solvents and synthesis methods are unavoidable parameters that control the overall structure of ZIF-8. This article presents a deep understanding of how solvents play their role in the crystallization and structure and therefore the properties of ZIF-8 by considering the polarity, viscosity, interfacial tension and molecular structure and comparing the behaviour of each solvent in every synthesis method. Also, to clearly realize their effect on the formation and final properties of ZIF-8, the crystallization process and mass transfer are discussed.

In the present study, organic pyrene-based derivatives were selected for NLO investigation.

Honey is a high-value, globally consumed, food product featuring a high market price strictly related to its origin. Moreover, honey origin has to be clearly stated on the label, and quality schemes are prescribed based on its geographical and botanical origin. Therefore, to enhance food quality, it is of utmost importance to develop analytical methods able to accurately and precisely discriminate honey origin. In this study, an all-time scientometric evaluation of the field is provided for the first time using a structured keyword on the Scopus database. The bibliometric analysis pinpoints that the botanical origin discrimination was the most studied authenticity issue, and chromatographic methods were the most frequently used for its assessment. Based on these results, we comprehensively reviewed analytical techniques that have been used in honey authenticity studies. Analytical breakthroughs and bottlenecks on methodologies to assess honey quality parameters using separation, bioanalytical, spectroscopic, elemental and isotopic techniques are presented. Emphasis is given to…

show less cytotoxicity and helps in regeneration of neuronal cells in animal model study. It establishes the fact that conjugation of different plant extract fraction for stabilization of gold nanoparticle may be responsible factor for enhancement of bioactive nature of green gold nanoparticle. In addition, the green gold nanoparticle show efficient photo-catalytic efficiency. Development of such bioactive gold nanoparticles will lead to functional materials for biomedical and therapeutic applications.

Water splitting is an important technology for alternative and sustainable energy storage, and a way for the production of hydrogen without generating pollution. In recent years, metal-organic frameworks (MOFs) have become the most capable multifunctional resources because of their high surface areas, tunable porosity, simple modification of compositions, and potential for use as precursors with a variety of morphological structures. Based on these qualities, many MOFs and their derived materials are utilized as electrocatalysts for the water splitting reaction. Herein, we assembled the relevant literature in recent years about MOF and MOF-derived materials for their eminent electrocatalytic activity in water splitting with useful strategies for the design and preparation of catalysts, along with challenges. This review summarizes the advancement in MOF materials, elucidating different strategies for its role in water splitting.

. The frequency dependence of the conductivity plot has been found to obey the universal Jonscher power law. Both AC and DC electrical conductivities are thoroughly studied as a function of frequency as well as temperature. The AC conductivity reveals that correlated barrier hopping (CBH) and non-overlapping small polaron tunneling (NSPT) models are suitable theoretical models to elucidate the conduction mechanisms existing in our compounds. Significantly, by increasing the temperature, the DC conductivity was increased, which verifies the semiconducting nature of the materials.

For the past 15 years, nanoscale metallic iron (nZVI) has been investigated as a new tool for the treatment of heavy metal contaminated water. The removal mechanisms depend on the type of heavy metals and their thermodynamic properties. A metal whose redox potential is more negative or close to the reduction potential of Fe(0) is removed by the reduction process, while the others will be mediated by precipitation, complexation or other sorption processes. This review summarises our contemporary knowledge of nZVI aqueous chemistry, synthesis methods, mechanisms and actions (practical experiences) of heavy metal (Cd, Cu and Pb) removal and challenges of nZVI practical applications. Its inner core (iron(0)) has reducing ability towards pollutants, while the iron oxide (FeO) outer shell provides reaction sites for chemisorption and electrostatic interactions with heavy metals. Emerging studies highlighted that nZVI surfaces will have negatively charged species at higher pH and have good affinity for the removal of positively charged species such as heavy metals. Different sizes, shapes…

was observed for the ZnO@PdO/Pd electrode. Furthermore, the observed low internal resistance of 0.4 Ω suggested effective electron- and ion diffusion. Thus, the superb electrochemical behavior of the ZnO@PdO/Pd nanocomposite was exposed, as verified by the significant redox behavior shown by cyclic voltammetry and galvanostatic charge-discharge.

This review provides a current summary of the major sources and distribution of ocean plastic contamination, their potential environmental effects, and prospects towards the mitigation of plastic pollution. A characterization between micro and macro plastics has been established, along with a comprehensive discussion of the most common plastic waste sources that end up in aquatic environments within these categories. Distribution of these sources stems mainly from improper waste management, road runoff, and wastewater pathways, along with potential routes of prevention. The environmental impact of ocean plastics is not yet fully understood, and as such, current research on the potential adverse health effects and impact on marine habitats has been discussed. With increasing environmental damage and economic losses estimated at $US 1.5 trillion, the challenge of ocean plastics needs to be at the forefront of political and societal discussions. Efforts to increase the feasibility of collected ocean plastics through value-added commercial products and development of an international…

Diamond thin films are known to have properties similar to bulk diamond and have applications in both industry and fundamental studies in academia. The high surface energy of diamond makes it extremely difficult to grow diamond films on foreign substrates. Hence, to grow diamond films on non-diamond substrates, a nucleation step is needed. In this review various techniques used for diamond nucleation/seeding will be discussed. At present electrostatic seeding by diamond nanoparticles is the most commonly used seeding technique for nanocrystalline growth. In this technique the substrate is dipped in a nanodiamond solution to form a mono layer of diamond seeds. These seeds when exposed to appropriate conditions grow to form diamond layers. This technique is suitable for most substrates. For heteroepitaxial growth, bias enhanced nucleation is the primary technique. In this technique the substrate is biased to form diamond nuclei in the initial stages of growth. This technique can be used for any conducting flat surface. For growth on ceramics, polishing by diamond grit or electrostatic…

Layered double hydroxides (LDH) with unique structure and excellent properties have been widely studied in recent years. LDH have found widespread applications in catalysts, polymer/LDH nanocomposites, anion exchange materials, supercapacitors, and fire retardants. The exfoliated LDH ultrathin nanosheets with a thickness of a few atomic layers enable a series of new opportunities in both fundamental research and applications. In this review, we mainly summarize the LDH exfoliation methods developed in recent years, the recent developments for the direct synthesis of LDH single-layer nanosheets, and the applications of LDH nanosheets in catalyzing oxygen evolution reactions, crosslinkers, supercapacitors and delivery carriers.

Metal-organic frameworks (MOFs) with efficient surface and structural properties have risen as a distinctive class of porous materials through the last few decades, which has enabled MOFs to gain attention in a wide range of applications like drug delivery, gas separation and storage, catalysis and sensors. Likewise, they have also emerged as efficient active materials in energy storage devices owing to their remarkable conducting properties. Metal-organic frameworks (MOFs) have garnered great interest in high-energy-density rechargeable batteries and super-capacitors. Herein the study presents their expanding diversity, structures and chemical compositions which can be tuned at the molecular level. It also aims to evaluate their inherently porous framework and how it facilitates electronic and ionic transportation through the charging and discharging cycles of lithium-ion batteries. In this review we have summarized the various synthesis paths to achieve a particular metal-organic framework. This study focuses mainly on the implementation of metal-organic frameworks as efficient…

The adsorption energy and electronic properties of sulfur dioxide (SO 2 ) adsorbed on different low-Miller index cobalt phosphide (CoP) surfaces were examined using density functional theory (DFT).

In recent years, the interest regarding the use of proteins as renewable resources has deeply intensified. The strongest impact of these biomaterials is clear in the field of smart medicines and biomedical engineering. Zein, a vegetal protein extracted from corn, is a suitable biomaterial for all the above-mentioned purposes due to its biodegradability and biocompatibility. The controlled drug delivery of small molecules, fabrication of bioactive membranes, and 3D assembly of scaffold for tissue regeneration are just some of the topics now being extensively investigated and reported in the literature. Herein, we review the recent literature on zein as a biopolymer and its applications in the biomedical world, focusing on the different shapes and sizes through which it can be manipulated.

The exfoliation of two-dimensional (2D) hexagonal boron nitride nanosheets (h-BNNSs) from bulk hexagonal boron nitride (h-BN) materials has received intense interest owing to their fascinating physical, chemical, and biological properties. Numerous exfoliation techniques offer scalable approaches for harvesting single-layer or few-layer h-BNNSs. Their structure is very comparable to graphite, and they have numerous significant applications owing to their superb thermal, electrical, optical, and mechanical performance. Exfoliation from bulk stacked h-BN is the most cost-effective way to obtain large quantities of few layer h-BN. Herein, numerous methods have been discussed to achieve the exfoliation of h-BN, each with advantages and disadvantages. Herein, we describe the existing exfoliation methods used to fabricate single-layer materials. Besides exfoliation methods, various functionalization methods, such as covalent, non-covalent, and Lewis acid-base approaches, including physical and chemical methods, are extensively described for the preparation of several h-BNNS derivatives.…

results against SARS-CoV-2. Finally, we recommend further advanced preclinical and clinical studies especially for tanshinone IIA (1) to be rapidly applied in COVID-19 management either alone or in combination with carnosic acid (2), rosmarinic acid (3), and/or salvianolic acid (4).

) suggested that the adsorption is spontaneous, being more spontaneous for AGO-CTS than GO-CTS hydrogels. Finally, the regeneration ability of the hydrogel adsorbents was studied in five consecutive cycles. The adsorbent maintained its efficiency at a relatively high level for three cycles but a considerable decrease was observed between the third and the fourth cycle, indicating that the hydrogels were recoverable for three cycles.

and increases the permeability of the tested molecule, partially compensating the desolvation penalty arising from the penetration of the drug into the biological membrane core. This effect was apparent in simulations where the formation of this interaction was prevented with the help of modified potentials, and in simulations with a similar compound to piracetam that was not able to form this intramolecular hydrogen bond due to a larger distance between the hydrogen bond donor and acceptor groups. These results were also supported by coarse-grained methods, which are becoming an important resource for sampling a larger chemical space of molecules, with reduced computational effort. Furthermore, entropy and enthalpy derived profiles were also obtained as the compounds translocated across the membrane, suggesting that, even though the process of formation of internal hydrogen bonds is entropically unfavorable, the enthalpic gain is such that the formation of these interactions is beneficial for the passive diffusion across cell membranes.

In order to reduce the cost and improve the performance of proton exchange membrane fuel cells (PEMFCs), it is imperative to further enhance the activity and durability of Pt based electrocatalysts for the oxygen reduction reaction (ORR). This article analyzes the latest advances in Pt-based ORR electrocatalysts, including the Pt alloys, Pt-M core-shell structures, particle size effects, support effects, doping in Pt/PtM and post treatment. In addition, the performance of some of the developed novel electrocatalysts in membrane electrode assemblies (MEA) is also included for comparison, as they are rarely available and the superior activity and durability exhibited in RDE frequently doesn't translate into MEA.

, furandicarboxylic acid, furfural alcohol, aromatics, levulinic acid, maleic acid, succinic acid, furoic acid, and cyclopentanone, particularly the advances in the catalytic valorization of furfural into useful chemicals in the last few years. The possible reaction mechanisms for the conversion of furfural into bio-chemicals are summarized and discussed. The future prospective and challenges in the utilization of furfural through chemo- and bio-catalysis are also put forward for the further design and optimization of catalytic processes for the conversion of furfural.

Smart edible coating films can be used in food packaging. For this application, they must have good physical and mechanical properties. Herein, chitosan-beeswax based film is used to preserve Le Conte pears postharvest. The chitosan-beeswax films were characterized using XRD, FT-IR, and SEM analysis. Moreover, all films showed good self-healing aptitudes ranging from 86.7 to 96.3. The film treated with pollen grains showed an enhanced water contact angle compared with the chitosan film. The chitosan-beeswax/pollen grain film exhibited a two-fold lower WVTR value compared to the chitosan film, and showed the tendency to increase the stiffness of the film. The elongation% at break was reduced from 35.81 to 14.09. Fruit quality parameters were determined in cold storage for 105 days during shelf life after a simulated marketing period of 7 days. All coated fruits successfully showed decrease in weight loss, decay and rate of softening. Therefore, chitosan-beeswax/pollen grains can be considered safe and effective coating for the fruit preservation.

) conditions. Upon complete thermal decomposition at 600 °C, the MOF produces predominantly tetragonal zirconia. TEM images of the thermally decomposed samples show that the shape of the original MOF crystal is maintained during the heating process in the inert and reductive environments, whereas under oxidative conditions, all of the carbon is burnt to carbon dioxide, leaving no carbon matrix as the support.

Chemical contaminants such as heavy metals, dyes, and organic oils seriously affect the environment and threaten human health. About 2 million tons of waste is released every day into the water system. Heavy metals are the largest contributor which cover about 31% of the total composition of water contaminants. Every day, approximately 14 000 people die due to environmental exposure to selected chemicals. Removal of these contaminants down to safe levels is expensive, high energy and unsustainable by current approaches such as oxidation, biodegradation, photocatalysis, precipitation, reverse osmosis and adsorption. A combination of biosorption and nanotechnology offers a new way to remediate these chemical contaminants. Nanostructured materials are proven to have higher adsorption capacities than the same material in its larger-scale form. Nanocellulose is very promising as a high-performance bioadsorbent due to its interesting characteristics of high adsorption capacity, high mechanical strength, hydrophilic surface chemistry, renewability and biodegradability. It has been proven…

-MXenes for six different organic dyes in aquatic media at different pH levels and ionic strengths. Our results strongly suggest the importance of the electrostatic interactions between the ionizable functional groups of MXenes and dyes for removal efficiency. The electrostatic repulsions between negatively charged MXenes and certain anionic dyes reduced the removal efficiencies of MXenes for these dyes in DI water; however, the presence of divalent cations significantly improved the removal efficiencies, possibly owing to the charge screening effects and like-charge attractions mediated by cation binding to the functionalities of dyes and MXenes. These results provide a rational strategy for optimizing the conditions for efficient removal of different types of organic dyes using MXenes.

Targeted drug delivery systems using PLGA as a nanocarrier for anti-cancer agents to improve efficacy and reduce toxicity in normal cells.

In recent years, spiro compounds have attracted significant interest in medicinal chemistry due to their numerous biological activities attributed primarily to their versatility and structural similarity to important pharmacophore centers. Currently, the development of drugs with potential antioxidant activities is of great importance since numerous investigations have shown that oxidative stress is involved in the development and progression of numerous diseases such as cancer, senile cataracts, kidney failure, diabetes, high blood pressure, cirrhosis, and neurodegenerative diseases, among others. This article provides an overview of the synthesis and various antioxidant activities found in naturally occurring and synthetic spiro compounds. Among the antioxidant activities reviewed are DPPH, ABTS, FRAP, anti-LPO, superoxide, xanthine oxidase, peroxide, hydroxyl, and nitric oxide tests, among others. Molecules that presented best results for these tests were spiro compounds G14, C12, D41, C18, C15, D5, D11, E1, and C14. In general, most active compounds are characterized for having…

Proton-exchange membrane fuel cells (PEMFCs) have received great attention as a potential alternative energy device for internal combustion engines due to their high conversion efficiency compared to other fuel cells. The main hindrance for the wide commercial adoption of PEMFCs is the high cost, low proton conductivity, and high fuel permeability of the state-of-the-art Nafion membrane. Typically, to improve the Nafion membrane, a wide range of strategies have been developed, in which efforts on the incorporation of carbon nanomaterial (CN)-based fillers are highly imperative. Even though many research endeavors have been achieved in relation to CN-based fillers applicable for Nafion, still their collective summary has rarely been reported. This review aims to outline the mechanisms involved in proton conduction in proton-exchange membranes (PEMs) and the significant requirements of PEMs for PEMFCs. This review also emphasizes the improvements achieved in the proton conductivity, fuel barrier properties, and PEMFC performance of Nafion membranes by incorporating carbon nanotubes,…

are introduced. At last, the promising research trends of BiOX-based photocatalysts are put forward. The main purpose is providing practical guidelines for developing high-performance BiOX photocatalysts.

Encouraging developments in the field of photocatalysis in last decades, biomolecules namely flavins have been observed to act as a catalyst in several photoredox-catalysed synthetic methodologies.

A magnetically recoverable polydopamine (PDA)-modified hydroxyapatite (HAp)/Fe 3 O 4 magnetic composite (HAp/Fe 3 O 4 /PDA) was synthesized to exploit its adsorption capacity to remove Zn 2+ from aqueous solution and the structural properties were examined.

The main aim of this study was to improve the spinnability of SA by adding PVA. The main parameters in producing nanofiber from the optimized SA:PVA ratio, including voltage, flow rate, and working space, were also optimized.

The development of cost-effective, efficient, and novel catalytic systems is always an important topic for heterogeneous catalysis from academia and industrial points of view. Heteroatom-doped carbon materials have gained more and more attention as effective heterogeneous catalysts to replace metal-based catalysts, because of their excellent physicochemical properties, outstanding structure characteristics, environmental compatibility, low cost, inexhaustible resources, and low energy consumption. Doping of heteroatoms can tailor the properties of carbons for different utilizations of interest. In comparison to pure carbon catalysts, these catalysts demonstrate superior catalytic activity in many organic reactions. This review highlights the most recent progress in synthetic strategies to fabricate metal-free heteroatom-doped carbon catalysts including single and multiple heteroatom-doped carbons and the catalytic applications of these fascinating materials in various organic transformations such as oxidation, hydrogenation, hydrochlorination, dehydrogenation,

We summarize a series of novel DNA-compatible chemistry reactions for DNA-encoded chemical library (DEL) building blocks and analyse the druggability of screened hit molecules via DELs in the past five years.

3D-printing or additive manufacturing is presently an emerging technology in the fourth industrial revolution that promises to reshape traditional manufacturing processes. The electrochemistry field can undoubtedly take advantage of this technology to fabricate electrodes to create a new generation of electrode sensor devices that could replace conventionally manufactured electrodes; glassy carbon, screen-printed carbon and carbon composite electrodes. In the electrochemistry research area, studies to date show that there is a demand for electrically 3D printable conductive polymer/carbon nanomaterial filaments where these materials can be printed out through an extrusion process based upon the fused deposition modelling (FDM) method. FDM could be used to manufacture novel electrochemical 3D printed electrode sensing devices for electrochemical sensor and biosensor applications. This is due to the FDM method being the most affordable 3D printing technique since conductive and non-conductive thermoplastic filaments are commercially available. Therefore, in this minireview, we focus…

, while the best isothermal description followed the Langmuir model. As a result, the adsorption process of heavy metals onto biochars was chemisorption on homogeneous monolayers, which was mainly controlled by cation exchange and surface precipitation mechanisms due to enriched oxygen-containing surface groups with ZnO-NP modification of biochar. The FTIR and EDS analysis data confirmed the important role of oxygen-containing surface groups, which significantly contributed to removal of heavy metals with extremely high adsorption capacities, comparable with other studies. In conclusion, due to very high adsorption capacities for metal cations, the cassava root husk-derived biochar modified with ZnO-NPs can be applied as the alternative, inexpensive, non-toxic and highly effective adsorbent in the removal of various toxic cations.

-methoxybenzyl ethers to generate the alcohols in high selectivity. A combination of DDQ and protic acid is known to oxidize several aromatic donors to the corresponding cation radicals. The excited-state DDQ converts benzyls, heteroarenes, fluoroarenes, benzene, and olefins into their radical cation forms as well as chloride and other anions into their respective radicals. These reactive intermediates have been employed for the generation of C-C and C-X (N, O, or Cl) bonds in the synthesis of valuable natural products and organic compounds. To the best of our knowledge, however, there is still no review article exclusively describing the applications of DDQ in organic synthesis. Therefore, in the present review, we provide an overview of DDQ-induced organic transformations with their scope, limitations and the proposed reaction mechanisms.

Psoriasis is a lingering inflammatory skin disease that attacks the immune system. The abnormal interactions between T cells, immune cells, and inflammatory cytokines causing the epidermal thickening. International guidelines have recommended topical treatments for mild to moderate psoriasis whilst systemic and phototherapy treatments for moderate to severe psoriasis. However, current therapeutic approaches have a wider extent to treat moderate to severe type of psoriasis especially since the emergence of diverse biologic agents. In the meantime, topical delivery of conventional treatments has prompted many unsatisfactory effects to penetrate through the skin (stratum corneum). By understanding the physiology of stratum corneum barrier functions, scientists have developed different types of lipid-based nanoparticles like solid lipid nanoparticles, nanostructured lipid carriers, nanovesicles, and nanoemulsions. These novel drug delivery systems help the poorly solubilised active pharmaceutical ingredient reaches the targeted site seamlessly because of the bioavailability feature of…

this method is largely affected by a number of factors such as the reaction temperature, duration of the reaction, type of solvent, pH of the solution, and the precipitating agent. Doping enhances the optical, magnetic, anti-bacterial, anti-microbial, and other properties of ZnO QDs. However, doping elements reside mostly on the surface of the QDs. The presence of doping elements inside the core is still a major challenge for doping techniques. In this review article, we have focused on pure, rare-earth, and transition metal-doped ZnO QD properties, and the various synthetic processes and applications. Quantum confinement effect is present in nearly every aspect of the QDs. The effect of quantum confinement has also been summarized in this manuscript. Furthermore, the doping of rare earth elements and transition metal, synthetic methods for different organic molecule-capped ZnO QDs, mechanisms for reactive oxygen species (ROS) generation, drug delivery system for cancer treatment, and many more application are discussed in this paper.

Isoquinoline alkaloids are a large group of natural products in which 1,2,3,4-tetrahydroisoquinolines (THIQ) form an important class. THIQ based natural and synthetic compounds exert diverse biological activities against various infective pathogens and neurodegenerative disorders. Due to these reasons, the THIQ heterocyclic scaffold has garnered a lot of attention in the scientific community which has resulted in the development of novel THIQ analogs with potent biological activity. The present review provides a much-needed update on the biological potential of THIQ analogs, their structural-activity relationship (SAR), and their mechanism of action. In addition, a note on commonly used synthetic strategies for constructing the core scaffold has also been discussed.

release test of ZIF8-Dox@PAA at pH 7.4 showed the low release rate of 24.7% even after 100 h. However, ZIF8-Dox@PAA at pH 4.0 exhibited four stages of release profiles, significantly enhanced release rate of 84.7% at the final release stage after 30 h. The release kinetics of ZIF8-Dox@PAA was analyzed by the sigmoidal Hill, exponential Weibull, and two-stage BiDoseResp models. The ZIF8-Dox@PAA nanocarrier demonstrated a promising theranostic nanoplatform equipped with fluorescent bioimaging, pH-responsive controlled drug release, and high drug loading capacity.

) and interactions with Gln92, Thr200, Asn66 and His68. Desmond's molecular dynamics simulations studies for 100 ns of compound 27 compared to reference SLC0111 provided useful structural insights of human carbonic anhydrase IX inhibition. Compound 27 with new chemical structure displayed both hydrophobic and hydrophilic stable interactions in the active site. RMSD, RMSF, RoG, H-bond and SASA analysis confirmed the stable binding of compound 27 with 5FL4 structure. In addition, MM-PBSA and MM-GBSA also affirm the docking results. We propose the designed compound 27 (predicted Ki = ∼0.07 nM) as the best theoretical lead which may further be experimentally studied for selective inhibition.

-MOF-74 catalyst. CO oxidation as a model reaction was then used to assess the catalytic performance of the prepared catalysts. The catalytic activity results show enhancement in the catalytic activities of monometallic MOFs after introducing another metal in the same framework and show an excellent improvement in CO conversion after loading with Pd nanoparticles. Furthermore, the samples that contain Pd nanoparticles exhibits higher catalytic activities which raised with increasing the content of Pd nanoparticles.

Water pollution is a severe and challenging issue threatening the sustainable development of human civilization. Besides other pollutants, waste fluid streams contain phenolic compounds. These have an adverse effect on the human health and marine ecosystem due to their toxic, mutagenic, and carcinogenic nature. Therefore, it is necessary to remove such phenolic pollutants from waste stream fluids prior to discharging to the environment. Different methods have been proposed to remove phenolic compounds from wastewater, including extraction using ionic liquids (ILs) and deep eutectic solvent (DES), a class of organic salts having melting point below 100 °C and tunable physicochemical properties. The purpose of this review is to present the progress in utilizing ILs and DES for phenolic compound extraction from waste fluid streams. The effects of IL structural characteristics, such as anion type, cation type, alkyl chain length, and functional groups will be discussed. In addition, the impact of key process parameters such as pH, phenol concentration, phase ratio, and temperature will…

(FA = formamidinium, MA = methylammonium). The neural network (NN) algorithm, which takes the interplay of cations and halide ions into account in predicting the bandgap, presents higher accuracy (with a RMSE of 0.05 eV and a Pearson coefficient larger than 0.99). Furthermore, the compositions of the mixed halide perovskites with desirable bandgaps and high iodide ratio for suppressing halide segregation are predicted by NN algorithm. These results highlight the power of machine learning in predicting the bandgap of the perovskites from their compositions and provide bandgap tuning directions for experiments.

on the catalyst surface, classifying common active sites, explaining the main role and additional role of the active sites in catalytic reactions, and discussing the methods to increase the number of active sites and their activation ability. Finally, the outlook for future research is presented. It is hoped this review could help researchers understand more about the activation of the nitrogen molecules and lead more efforts into research on nitrogen fixation photocatalysts.

. Phosphate groups are linked to cellulose through a P-O-C bond in the form of orthophosphate and pyrophosphates. Furthermore, thermal properties of the phosphorylated cellulosic fibers were investigated and a new degradation mechanism was proposed.

model. This study provides a deeper understanding of the modification of electronic and magnetic properties of N-doped graphene by controlling the bond configuration and the number of nitrogen dopants.

The synthesis of Lu 2 Cu 2 O 5 –Lu 2 O 3 nanocomposites via a simple auto-combustion approach and their excellent performance in the removal of organic pollutants under sunlight is presented for the first time.

This study reports plant mediated-copper oxide nanoparticles synthesis from Annona squamosa and their real-life application in agricultural domain for label-free detection of H 2 O 2 and its antibacterial efficiency for combating rice crop pathogen.

Biodiesel is one of the main biofuels used to replace fossil resources, and is mainly produced from esterification and transesterification of fatty acids and oils catalyzed by acids, bases or enzymes. Among the existing catalysts, metal oxides and their derivatives play an important role because of their high catalytic activity and low cost. ZnO is a metal oxide and its related nanomaterials are easy to prepare, which gives ZnO superior reactivity and extensive applications. Suitably modified ZnO nanomaterials typically have high specific surface areas, suitable pore sizes, and enhanced catalytic performance in the production of biodiesel. The present review introduces the application progress of ZnO catalysts in biodiesel preparation. The current shortcomings and future challenges of the basic heterogeneous catalytic systems for biodiesel production are also discussed.

In the past decades, drag-reduction surfaces have attracted more and more attention due to their potentiality and wide applications in various fields such as traffic, energy transportation, agriculture, textile industry, and military. However, there are still some drag-reduction materials that need to be deeply explored. Fortunately, natural creatures always have the best properties after long-term evolution; aquatic organisms have diversified surface microstructures and drag-reducing materials, which provide design templates for the development of thriving artificial underwater drag-reduction materials. Aquatic animals are tamed by the current while fighting against the water, and thus have excellent drag reduction that is unparalleled in water. Inspired by biological principles, using aquatic animals as a bionic object to develop and reduce frictional resistance in fluids has attracted more attention in the past few years. More and more aquatic animals bring new inspiration for drag-reduction surfaces and a tremendous amount of research effort has been put into the study of…

and glucose, respectively. Furthermore, the specificity of detection of glucose was compared with other sugar species interference such as sucrose, lactose and maltose. In addition, the detection of ascorbic acid and sodium thiosulfate was also performed upon the inhibition of TMB oxidation. Based on the high catalytic activity, affinity and wide linear range, the as-prepared Cu-MOF may be used for artificial enzyme mimics in the fields of catalysis, biosensors, medicines and food industry.

O, and DDQ, in combination with Brønsted or Lewis acids, and the surface-mediated reaction has found especially wide applications in PAH synthesis. Undoubtedly, the utility of the Scholl reaction is supreme in the construction of nanographene and their heterocyclic analogues. The detailed analysis of the progress achieved in this field reveals that many groups have contributed by pushing the boundary of structural possibilities, expanding into surface-assisted cyclodehydrogenation and developing new reagents. In this review, we highlight and discuss the recent modifications in the Scholl reaction for nanographene synthesis using numerous oxidant systems. In addition, the merits or demerits of each oxidative reagent is described herein.

. Using 0.5 μm polystyrene beads as model microplastics, a removal efficiency of more than 90% within 5 min was achieved. Since microplastics mostly accumulate in the gut of animals, rat intestine IEC18 cells exposed to purified water from the microbead suspension were risk assessed, revealing that water purified using the coagulation-based method reduced oxidative stress and inflammatory cytokines to levels similar to those in cells exposed to water without microbeads.

Activated carbon produced from agricultural products and wastes has been applied widely to remove pollutants in the field of waste water treatment. However, the cost of this adsorbent depends so much on the raw material sources. Therefore, the approach of producing activated carbon from agricultural waste is strongly recommended due to economic advantages and environmental protection. One of the potential feed-stocks for the activated carbon production is cashew nut shell (CNS) waste which could reduce the negative impacts to the environment from the cashew nut processing industry and simultaneously enhance the values of the related products. This study focused on evaluating the influences of variable factors, such as activation temperature and time, on the properties of the activated carbon obtained from CNS. Methylene blue (MB) adsorption was applied to understand the adsorption mechanism of the products. The results show that increasing the activation temperature led to a rise in the adsorption capacity of the activated carbon within the temperature range of 800 to 850 °C.…

In this research, a single-stage batch adsorber was designed for removal of brilliant green dye from aqueous solutions using activated carbon derived from date pits based on the Freundlich isotherm which was the best-fitted isotherm model.

harvesting triplet state. Furthermore, previously reported fluorescent materials are described and categorized based on luminescence behaviors on account of the Stokes shifts value. This review will serve as a rationalized introduction and reference for researchers who are interested in exploring large or mega Stokes shift molecules, and will motivate new strategies along with instigation of persistent efforts in this prominent subject area with great avenues.

In recent years, the demand for non-surfactant based Pickering emulsions in many industrial applications has grown significantly because of the option to select biodegradable and sustainable materials with low toxicity as emulsion stabilisers. Usually, emulsions are a dispersion system, where synthetic surfactants or macromolecules stabilise two immiscible phases (typically water and oil phases) to prevent coalescence. However, synthetic surfactants are not always a suitable choice in some applications, especially in pharmaceuticals, food and cosmetics, due to toxicity and lack of compatibility and biodegradability. Therefore, this review reports recent literature (2018-2021) on the use of comparatively safer biodegradable polysaccharide particles, proteins, lipids and combinations of these species in various Pickering emulsion formulations. Also, an overview of the various tuneable factors associated with the functionalisation or surface modification of these solid particles, that govern the stability of the Pickering emulsions is provided.

. The surface energy and its acid-base component are sensitive to the delamination methods and MXene compositions, while the dispersion component of the surface energy is stable. These findings will provide valuable insight and guidance for measuring contact angles of MXene films and the rational design and synthesis of MXene-based films, composites, coatings, and energy storage devices.

The non-specific distribution, non-selectivity towards cancerous cells, and adverse off-target side effects of anticancer drugs and other therapeutic molecules lead to their inferior clinical efficacy. Accordingly, ultrasound-based targeted delivery of therapeutic molecules loaded in smart nanocarriers is currently gaining wider acceptance for the treatment and management of cancer. Nanobubbles (NBs) are nanosize carriers, which are currently used as effective drug/gene delivery systems because they can deliver drugs/genes selectively to target sites. Thus, combining the applications of ultrasound with NBs has recently demonstrated increased localization of anticancer molecules in tumor tissues with triggered release behavior. Consequently, an effective therapeutic concentration of drugs/genes is achieved in target tumor tissues with ultimately increased therapeutic efficacy and minimal side-effects on other non-cancerous tissues. This review illustrates present developments in the field of ultrasound-nanobubble combined strategies for targeted cancer treatment. The first part of…

biodegradation and swelling behavior demonstrated that increasing the amount of NCDs up to 0.06% decreased the swelling ratio and weight loss of the hydrogels. The composite hydrogels are biocompatible, as verified by the MTT assay of MG-63 cells. The N-doped graphene quantum dots considerably affect degradation and interaction within the cells and hydrogels.

Stokes radius (dynamic ionic radius) of the alkali metal ions versus the ionic radius ( R ion ) at 303 K. The dotted line is a guide for the 1 : 1 relation.

) increased by increasing the doses of pyrimidine derivatives and the temperature of the medium. Weight loss data revealed the better adsorption of MA-1232 on the Cu surface at increased inhibitor dose, reaching a maximum efficiency of 99.14% at a dose of 21 μM at 45 °C. The best description of the adsorption of the investigated derivatives on the copper surface was given by the Langmuir isotherm. Some important thermodynamic parameters for the studied inhibitors were computed and are discussed herein. The polarization studies showed that the pyrimidine-bichalcophenes act as mixed inhibitors. Computational chemical approaches were used with informative yields, including quantum-chemical and molecular dynamics simulation techniques, which agree with the experimental results. The results obtained from all tested methods are strongly accepted.

= 298 K, which was superior to individual graphene and many other adsorbents. The results indicated that the recovered nanomaterials endure 4 times recyclability retaining up to 89% lead uptake efficiency. To complement the experimental study, DFT calculations were performed to investigate the stability of the formed G-CdO composite compared to CdO NPs; the reactivity of G-CdO compared to plain graphene as well as the interaction insights between graphene and CdO clusters were studied using natural-bond-orbital (NBO), electron-localization-function (ELF) and reduced-density-gradient (RDG) analyses.

) determined using Tauc's equation for the direct transition is increased from 2.2 to 2.65 eV when water is totally replaced by ethanol. The feasibility of both CuO samples as photocatalysts for the degradation of Congo red was tested. CuO prepared in pure water showed remarkably high efficiency during the first 25 min of illumination. Both samples showed complete dye removal after 35 min. Ultimately, this work presents a simple and green approach for the preparation of CuO NPs with tunable particle size, varied morphological shapes, high surface area, and different structural and optical properties merely through controlling the ethanol content in water.