The 100 most-cited articles in Materials, 2021

The automotive lightweighting trends, being driven by sustainability, cost, and performance, that create the enormous demand for lightweight materials and design concepts, are assessed as a part of the circular economy solutions in modern mobility and transportation. The current strategies that aim beyond the basic weight reduction and cover also the structural efficiency as well as the economic and environmental impact are explained with an essence of guidelines for materials selection with an eco-friendly approach, substitution rules, and a paradigm of the multi-material design. Particular attention is paid to the metallic alloys sector and progress in global R&D activities that cover the "lightweight steel", conventional aluminum, and magnesium alloys, together with well-established technologies of components manufacturing and future-oriented solutions, and with both adjusting to a transition from internal combustion engines to electric vehicles. Moreover, opportunities and challenges that the lightweighting creates are discussed with strategies of achieving its goals through…

Additive manufacturing (AM, 3D printing) is used in many fields and different industries. In the medical and dental field, every patient is unique and, therefore, AM has significant potential in personalized and customized solutions. This review explores what additive manufacturing processes and materials are utilized in medical and dental applications, especially focusing on processes that are less commonly used. The processes are categorized in ISO/ASTM process classes: powder bed fusion, material extrusion, VAT photopolymerization, material jetting, binder jetting, sheet lamination and directed energy deposition combined with classification of medical applications of AM. Based on the findings, it seems that directed energy deposition is utilized rarely only in implants and sheet lamination rarely for medical models or phantoms. Powder bed fusion, material extrusion and VAT photopolymerization are utilized in all categories. Material jetting is not used for implants and biomanufacturing, and binder jetting is not utilized for tools, instruments and parts for medical devices. The…

Metal-organic frameworks represent a porous class of materials that are build up from metal ions or oligonuclear metallic complexes and organic ligands. They can be considered as sub-class of coordination polymers and can be extended into one-dimension, two-dimensions, and three-dimensions. Depending on the size of the pores, MOFs are divided into nanoporous, mesoporous, and macroporous items. The latter two are usually amorphous. MOFs display high porosity, a large specific surface area, and high thermal stability due to the presence of coordination bonds. The pores can incorporate neutral molecules, such as solvent molecules, anions, and cations, depending on the overall charge of the MOF, gas molecules, and biomolecules. The structural diversity of the framework and the multifunctionality of the pores render this class of materials as candidates for a plethora of environmental and biomedical applications and also as catalysts, sensors, piezo/ferroelectric, thermoelectric, and magnetic materials. In the present review, the synthetic methods reported in the literature for preparing…

Since the last few years, the growing interest in the use of natural and synthetic antioxidants as functional food ingredients and dietary supplements, is observed. The imbalance between the number of antioxidants and free radicals is the cause of oxidative damages of proteins, lipids, and DNA. The aim of the study was the review of recent developments in antioxidants. One of the crucial issues in food technology, medicine, and biotechnology is the excess free radicals reduction to obtain healthy food. The major problem is receiving more effective antioxidants. The study aimed to analyze the properties of efficient antioxidants and a better understanding of the molecular mechanism of antioxidant processes. Our researches and sparing literature data prove that the ligand antioxidant properties complexed by selected metals may significantly affect the free radical neutralization. According to our preliminary observation, this efficiency is improved mainly by the metals of high ion potential, e.g., Fe(III), Cr(III), Ln(III), Y(III). The complexes of delocalized electronic charge are…

Natural extracts are the source of many antioxidant substances. They have proven useful not only as supplements preventing diseases caused by oxidative stress and food additives preventing oxidation but also as system components for the production of metallic nanoparticles by the so-called green synthesis. This is important given the drastically increased demand for nanomaterials in biomedical fields. The source of ecological technology for producing nanoparticles can be plants or microorganisms (yeast, algae, cyanobacteria, fungi, and bacteria). This review presents recently published research on the green synthesis of nanoparticles. The conditions of biosynthesis and possible mechanisms of nanoparticle formation with the participation of bacteria are presented. The potential of natural extracts for biogenic synthesis depends on the content of reducing substances. The assessment of the antioxidant activity of extracts as multicomponent mixtures is still a challenge for analytical chemistry. There is still no universal test for measuring total antioxidant capacity (TAC). There are…

Photocatalysis based technologies have a key role in addressing important challenges of the ecological transition, such as environment remediation and conversion of renewable energies. Photocatalysts can in fact be used in hydrogen (H2) production (e.g., via water splitting or photo-reforming of organic substrates), CO2 reduction, pollution mitigation and water or air remediation via oxidation (photodegradation) of pollutants. Titanium dioxide (TiO2) is a “benchmark” photocatalyst, thanks to many favorable characteristics. We here review the basic knowledge on the charge carrier processes that define the optical and photophysical properties of intrinsic TiO2. We describe the main characteristics and advantages of TiO2 as photocatalyst, followed by a summary of historical facts about its application. Next, the dynamics of photogenerated electrons and holes is reviewed, including energy levels and trapping states, charge separation and charge recombination. A section on optical absorption and optical properties follows, including a discussion on TiO2 photoluminescence and on the…

This paper provides a state-of-the-art report on the up-to-date research on the emerging 3D concrete printing technology from the concrete materials perspective. It reviews the recent research focused on understanding and characterizing the rheological necessities of the concrete printing process and discusses how the researchers are tailoring compatible mix proportions for the 3D concrete printing process by using eco-friendly binders, waste aggregates, chemical admixtures, and nano-additives. This paper systematically evaluates anisotropic behavior in the mechanical properties of printed concrete and establishes an order for anisotropic behavior in the compressive, flexural, and tensile strengths along three different axes (X, Y, and Z axes) of printed concrete. It evaluates the ratio of flexural strength to the compressive strength of printed concrete along the above three axes. This article explains the influence of variation of printing process parameters on the mechanical properties and discusses reinforcement approaches used for increasing structural performance. The…

Conventionally, in a linear economy, C&D (Construction and Demolition) waste was considered as zero value materials, and, as a result of that, most C&D waste materials ended up in landfills. In recent years, with the increase in the awareness around sustainability and resource management, various countries have started to explore new models to minimize the use of limited resources which are currently overused, mismanaged, or quickly depleting. In this regard, the implementation of CE (Circular Economy) has emerged as a potential model to minimize the negative impact of C&D wastes on the environment. However, there are some challenges hindering a full transition to CE in the construction and demolition sectors. Therefore, this review paper aims to critically scrutinize different aspects of C&D waste and how CE can be integrated into construction projects. Reviewing of the literature revealed that the barriers in the implementation of CE in C&D waste sectors fall in five main domains, namely legal, technical, social, behavioral, and economic aspects. In this context, it was found that…

Hydrogels are hydrophilic 3D networks that are able to ingest large amounts of water or biological fluids, and are potential candidates for biosensors, drug delivery vectors, energy harvester devices, and carriers or matrices for cells in tissue engineering. Natural polymers, e.g., cellulose, chitosan and starch, have excellent properties that afford fabrication of advanced hydrogel materials for biomedical applications: biodegradability, biocompatibility, non-toxicity, hydrophilicity, thermal and chemical stability, and the high capacity for swelling induced by facile synthetic modification, among other physicochemical properties. Hydrogels require variable time to reach an equilibrium swelling due to the variable diffusion rates of water sorption, capillary action, and other modalities. In this study, the nature, transport kinetics, and the role of water in the formation and structural stability of various types of hydrogels comprised of natural polymers are reviewed. Since water is an integral part of hydrogels that constitute a substantive portion of its composition, there is a…

Construction is among the leading industries/activities contributing the largest carbon footprint. This review paper aims to promote awareness of the sources of carbon footprint in the construction industry, from design to operation and management during manufacturing, transportation, construction, operations, maintenance and management, and end-of-life deconstruction phases. In addition, it summarizes the latest studies on carbon footprint reduction strategies in different phases of construction by the use of alternative additives in building materials, improvements in design, recycling construction waste, promoting the utility of alternative water resources, and increasing efficiencies of water technologies and other building systems. It was reported that the application of alternative additives/materials or techniques/systems can reduce up to 90% of CO2 emissions at different stages in the construction and building operations. Therefore, this review can be beneficial at the stage of conceptualization, design, and construction to assist clients and stakeholders in selecting…

Carbon nanomaterials (CNMs) have received tremendous interest in the area of nanotechnology due to their unique properties and flexible dimensional structure. CNMs have excellent electrical, thermal, and optical properties that make them promising materials for drug delivery, bioimaging, biosensing, and tissue engineering applications. Currently, there are many types of CNMs, such as quantum dots, nanotubes, nanosheets, and nanoribbons; and there are many others in development that promise exciting applications in the future. The surface functionalization of CNMs modifies their chemical and physical properties, which enhances their drug loading/release capacity, their ability to target drug delivery to specific sites, and their dispersibility and suitability in biological systems. Thus, CNMs have been effectively used in different biomedical systems. This review explores the unique physical, chemical, and biological properties that allow CNMs to improve on the state of the art materials currently used in different biomedical applications. The discussion also embraces the emerging…

Monitoring human health for early detection of disease conditions or health disorders is of major clinical importance for maintaining a healthy life. Sensors are small devices employed for qualitative and quantitative determination of various analytes by monitoring their properties using a certain transduction method. A "real-time" biosensor includes a biological recognition receptor (such as an antibody, enzyme, nucleic acid or whole cell) and a transducer to convert the biological binding event to a detectable signal, which is read out indicating both the presence and concentration of the analyte molecule. A wide range of specific analytes with biomedical significance at ultralow concentration can be sensitively detected. In nano(bio)sensors, nanoparticles (NPs) are incorporated into the (bio)sensor design by attachment to the suitably modified platforms. For this purpose, metal nanoparticles have many advantageous properties making them useful in the transducer component of the (bio)sensors. Gold, silver and platinum NPs have been the most popular ones, each form of these…

Surfactants are essential in the manufacture of polymeric nanoparticles by emulsion formation methods and to preserve the stability of carriers in liquid media. The deposition of non-ionic surfactants at the interface allows a considerable reduction of the globule of the emulsion with high biocompatibility and the possibility of oscillating the final sizes in a wide nanometric range. Therefore, this review presents an analysis of the three principal non-ionic surfactants utilized in the manufacture of polymeric nanoparticles; polysorbates, poly(vinyl alcohol), and poloxamers. We included a section on general properties and uses and a comprehensive compilation of formulations with each principal non-ionic surfactant. Then, we highlight a section on the interaction of non-ionic surfactants with biological barriers to emphasize that the function of surfactants is not limited to stabilizing the dispersion of nanoparticles and has a broad impact on pharmacokinetics. Finally, the last section corresponds to a recommendation in the experimental approach for choosing a surfactant applying…

The recent introduction of three-dimensional (3D) printing is revolutionizing dentistry and is even being applied to orthodontic treatment of malocclusion. Clear, personalized, removable aligners are a suitable alternative to conventional orthodontic appliances, offering a more comfortable and efficient solution for patients. Including improved oral hygiene and aesthetics during treatment. Contemporarily, clear aligners are produced by a thermoforming process using various types of thermoplastic materials. The thermoforming procedure alters the properties of the material, and the intraoral environment further modifies the properties of a clear aligner, affecting overall performance of the material. Direct 3D printing offers the creation of highly precise clear aligners with soft edges, digitally designed and identically reproduced for an entire set of treatment aligners; offering a better fit, higher efficacy, and reproducibility. Despite the known benefits of 3D printing and the popularity of its dental applications, very limited technical and clinical data are available in the…

In recent years, many alloys as well as composites of aluminium were developed for enhanced material performance. AA 6061 is an aluminium alloy that has extensive applications due to its superior material characteristics. It is a popular choice of matrix for aluminium matrix composite (AMC) fabrication. This study provides a review on AA 6061 aluminium alloy matrix composites produced through the stir-casting process. It focusses on conventional stir-casting fabrication, process parameters, various reinforcements used, and the mechanical properties of the AA 6061 composites. Several research studies indicated that the stir-casting method is widely used and suitable for fabricating AA 6061 composites with reinforcements such as SiC, B4C, Al2O3, TiC, as well as other inorganic, organic, hybrid, and nanomaterials. The majority of the studies showed that an increase in the reinforcement content enhanced the mechanical and tribological properties of the composites. Furthermore, hybrid composites showed better material properties than single reinforcement composites. The usage of…

Machine learning techniques are widely used algorithms for predicting the mechanical properties of concrete. This study is based on the comparison of algorithms between individuals and ensemble approaches, such as bagging. Optimization for bagging is done by making 20 sub-models to depict the accurate one. Variables like cement content, fine and coarse aggregate, water, binder-to-water ratio, fly-ash, and superplasticizer are used for modeling. Model performance is evaluated by various statistical indicators like mean absolute error (MAE), mean square error (MSE), and root mean square error (RMSE). Individual algorithms show a moderate bias result. However, the ensemble model gives a better result with R2 = 0.911 compared to the decision tree (DT) and gene expression programming (GEP). K-fold cross-validation confirms the model’s accuracy and is done by R2, MAE, MSE, and RMSE. Statistical checks reveal that the decision tree with ensemble provides 25%, 121%, and 49% enhancement for errors like MAE, MSE, and RMSE between the target and outcome response.

Heavy metal is released from many industries into water. Before the industrial wastewater is discharged, the contamination level should be reduced to meet the recommended level as prescribed by the local laws of a country. They may be poisonous or cancerous in origin. Their presence does not only damage people, but also animals and vegetation because of their mobility, toxicity, and non-biodegradability into aquatic ecosystems. The review comprehensively discusses the progress made by various adsorbents such as natural materials, synthetic, agricultural, biopolymers, and commercial for extraction of the metal ions such as Ni2+, Cu2+, Pb2+, Cd2+, As2+ and Zn2+ along with their adsorption mechanisms. The adsorption isotherm indicates the relation between the amount adsorbed by the adsorbent and the concentration. The Freundlich isotherm explains the effective physical adsorption of the solute particle from the solution on the adsorbent and Langmuir isotherm gives an idea about the effect of various factors on the adsorption process. The adsorption kinetics data provide valuable…

The adoption of green technology is very important to protect the environment and thus there is a need for improving the existing methods for the fabrication of carbon materials. As such, this work proposes to discuss, interrogate, and propose viable hydrothermal, solvothermal, and other advanced carbon materials synthesis methods. The synthesis approaches for advanced carbon materials to be interrogated will include the synthesis of carbon dots, carbon nanotubes, nitrogen/titania-doped carbons, graphene quantum dots, and their nanocomposites with solid/polymeric/metal oxide supports. This will be performed with a particular focus on microwave-assisted solvothermal and hydrothermal synthesis due to their favourable properties such as rapidity, low cost, and being green/environmentally friendly. These methods are regarded as important for the current and future synthesis and modification of advanced carbon materials for application in energy, gas separation, sensing, and water treatment. Simultaneously, the work will take cognisance of methods reducing the fabrication costs and…

Titanium and its alloys, specially Ti6Al4V, are among the most employed materials in orthopedic and dental implants. Cells response and osseointegration of implant devices are strongly dependent on the body-biomaterial interface zone. This interface is mainly defined by proteins: They adsorb immediately after implantation from blood and biological fluids, forming a layer on implant surfaces. Therefore, it is of utmost importance to understand which features of biomaterials surfaces influence formation of the protein layer and how to guide it. In this paper, relevant literature of the last 15 years about protein adsorption on titanium-based materials is reviewed. How the surface characteristics affect protein adsorption is investigated, aiming to provide an as comprehensive a picture as possible of adsorption mechanisms and type of chemical bonding with the surface, as well as of the characterization techniques effectively applied to model and real implant surfaces. Surface free energy, charge, microroughness, and hydroxylation degree have been found to be the main surface parameters…

Areal 3D analysis of surface texture gives more opportunities than a study of 2D profiles. Surface topography evaluation, considered as 3D dimensional analysis in micro or nanoscales, plays an important role in many fields of science and life. Among many texture parameters, those connected with height are the most often used. However, there are many other parameters and functions that can provide additional important information regarding functional behaviour of surfaces in different applications. The knowledge about the functional importance of various surface properties is low. This review tries to fill this gap. Surface texture parameters are presented in various groups: height, spatial, hybrid, functional, feature, and others. Based on experiences of the present authors and literature review, the relationships among various surface parameters and functional properties are described. A proposal of a selection of parameters on the basis of their functional significations is provided. Considerations for future challenges are addressed.

It is crucial that proper engineering structures are designed as energy absorbers for high dynamic loading situations, such as accidents, blasts, or impacts. The role of such structures is to absorb the high kinetic energy as strain energy through irreversible deformation of the structure. Many types of energy absorbers were designed for different dynamic high strain rate applications. One of these structures are sandwich structures. The aim of this review paper is to provide a general review on the type of sandwich structures that have been designed as energy absorbers and their performance in crashworthiness and blast related applications. The focus is on the type of core structures being used, namely foam and architected cores. It was found from the review that sandwich structures are viable candidates for such applications not only because of their light weight, but also due to the high-energy absorption capabilities. The work presented in this review paper shows that the data from the literature on this topic are vast and do not converge to any particular sandwich structure…

The use of bioactive glasses in dentistry, reconstructive surgery, and in the treatment of infections can be considered broadly beneficial based on the emerging literature about the potential bioactivity and biocompatibility of these materials, particularly with reference to Bioglass® 45S5, BonAlive® and 19-93B3 bioactive glasses. Several investigations have been performed (i) to obtain bioactive glasses in different forms, such as bulk materials, powders, composites, and porous scaffolds and (ii) to investigate their possible applications in the biomedical field. Although in vivo studies in animals provide us with an initial insight into the biological performance of these systems and represent an unavoidable phase to be performed before clinical trials, only clinical studies can demonstrate the behavior of these materials in the complex physiological human environment. This paper aims to carefully review the main published investigations dealing with clinical trials in order to better understand the performance of bioactive glasses, evaluate challenges, and provide an essential…

Sustaining the vital functions of cells outside the organism requires strictly defined parameters. In order to ensure their optimal growth and development, it is necessary to provide a range of nutrients and regulators. Hydrogels are excellent materials for 3D in vitro cell cultures. Their ability to retain large amounts of liquid, as well as their biocompatibility, soft structures, and mechanical properties similar to these of living tissues, provide appropriate microenvironments that mimic extracellular matrix functions. The wide range of natural and synthetic polymeric materials, as well as the simplicity of their physico-chemical modification, allow the mechanical properties to be adjusted for different requirements. Sodium alginate-based hydrogel is a frequently used material for cell culture. The lack of cell-interactive properties makes this polysaccharide the most often applied in combination with other materials, including gelatin. The combination of both materials increases their biological activity and improves their material properties, making this combination a…

Gelatin is a natural biopolymer derived from collagen. Due to its many advantages, such as swelling capacity, biodegradability, biocompatibility, and commercial availability, gelatin is widely used in the field of pharmacy, medicine, and the food industry. Gelatin solutions easily form hydrogels during cooling, however, the materials are mechanically poor. To improve their properties, they are often chemically crosslinked. The cross-linking agents are divided into two groups: Zero-length and non-zero-length cross-linkers. In this study, gelatin was cross-linked by three different cross-linking agents: EDC-NHS, as a typically used cross-linker, and also squaric acid (SQ) and dialdehyde starch (DAS), as representatives of a second group of cross-linkers. For all prepared gelatin hydrogels, mechanical strength tests, thermal analysis, infrared spectroscopy, swelling ability, and SEM images were performed. The results indicate that the dialdehyde starch is a better cross-linking agent for gelatin than EDC-NHS. Meanwhile, the use of squaric acid does not give beneficial changes to the…

hybridized carbon atoms) and is the center of attention for researchers due to its extraordinary physicochemical (e.g., optical transparency, electrical, thermal conductivity, and mechanical) properties. Graphene can be synthesized using top-down or bottom-up approaches and is used in the electronics and medical (e.g., drug delivery, tissue engineering, biosensors) fields as well as in photovoltaic systems. However, the mass production of graphene and the means of transferring monolayer graphene for commercial purposes are still under investigation. When graphene layers are stacked as flakes, they have substantial impacts on the properties of graphene-based materials, and the layering of graphene obtained using different approaches varies. The determination of number of graphene layers is very important since the properties exhibited by monolayer graphene decrease as the number of graphene layer per flake increases to 5 as few-layer graphene, 10 as multilayer graphene, and more than 10 layers, when it behaves like bulk graphite. Thus, this review summarizes graphene developments and…

Plastic production has been rapidly growing across the world and, at the end of their use, many of the plastic products become waste disposed of in landfills or dispersed, causing serious environmental and health issues. From a sustainability point of view, the conversion of plastic waste to fuels or, better yet, to individual monomers, leads to a much greener waste management compared to landfill disposal. In this paper, we systematically review the potential of pyrolysis as an effective thermochemical conversion method for the valorization of plastic waste. Different pyrolysis types, along with the influence of operating conditions, e.g., catalyst types, temperature, vapor residence time, and plastic waste types, on yields, quality, and applications of the cracking plastic products are discussed. The quality of pyrolysis plastic oil, before and after upgrading, is compared to conventional diesel fuel. Plastic oil yields as high as 95 wt.% can be achieved through slow pyrolysis. Plastic oil has a heating value approximately equivalent to that of diesel fuel, i.e., 45 MJ/kg, no…

Diamond-like carbon (DLC) films have been extensively applied in industries owing to their excellent characteristics such as high hardness. In particular, there is a growing demand for their use as protective films for mechanical parts owing to their excellent wear resistance and low friction coefficient. DLC films have been deposited by various methods and many deviate from the DLC regions present in the ternary diagrams proposed for sp3 covalent carbon, sp2 covalent carbon, and hydrogen. Consequently, redefining the DLC region on ternary diagrams using DLC coatings for mechanical and electrical components is urgently required. Therefore, we investigate the sp3 ratio, hydrogen content, and other properties of 74 types of amorphous carbon films and present the classification of amorphous carbon films, including DLC. We measured the sp3 ratios and hydrogen content using near-edge X-ray absorption fine structure and Rutherford backscattering-elastic recoil detection analysis under unified conditions. Amorphous carbon films were widely found with nonuniform distribution. The number of…

High temperature severely affects the nature of the ingredients used to produce concrete, which in turn reduces the strength properties of the concrete. It is a difficult and time-consuming task to achieve the desired compressive strength of concrete. However, the application of supervised machine learning (ML) approaches makes it possible to initially predict the targeted result with high accuracy. This study presents the use of a decision tree (DT), an artificial neural network (ANN), bagging, and gradient boosting (GB) to forecast the compressive strength of concrete at high temperatures on the basis of 207 data points. Python coding in Anaconda navigator software was used to run the selected models. The software requires information regarding both the input variables and the output parameter. A total of nine input parameters (water, cement, coarse aggregate, fine aggregate, fly ash, superplasticizers, silica fume, nano silica, and temperature) were incorporated as the input, while one variable (compressive strength) was selected as the output. The performance of the employed ML…

Multi-materials of metal-polymer and metal-composite hybrid structures (MMHSs) are highly demanded in several fields including land, air and sea transportation, infrastructure construction, and healthcare. The adoption of MMHSs in transportation industries represents a pivotal opportunity to reduce the product's weight without compromising structural performance. This enables a dramatic reduction in fuel consumption for vehicles driven by internal combustion engines as well as an increase in fuel efficiency for electric vehicles. The main challenge for manufacturing MMHSs lies in the lack of robust joining solutions. Conventional joining processes, e.g., mechanical fastening and adhesive bonding involve several issues. Several emerging technologies have been developed for MMHSs' manufacturing. Different from recently published review articles where the focus is only on specific categories of joining processes, this review is aimed at providing a broader and systematic view of the emerging opportunities for hybrid thin-walled structure manufacturing. The present review paper…

The cross-linking density influences the physicochemical properties of cyclodextrin-based nanosponges (CD-NSs). Although the effect of the cross-linker type and content on the NSs performance has been investigated, a detailed study of the cross-linking density has never been performed. In this contribution, nine ester-bridged NSs based on β-cyclodextrin (β-CD) and different quantities of pyromellitic dianhydride (PMDA), used as a cross-linking agent in stoichiometric proportions of 2, 3, 4, 5, 6, 7, 8, 9, and 10 moles of PMDA for each mole of CD, were synthesized and characterized in terms of swelling and rheological properties. The results, from the swelling experiments, exploiting Flory-Rehner theory, and rheology, strongly showed a cross-linker content-dependent behavior. The study of cross-linking density allowed to shed light on the efficiency of the synthesis reaction methods. Overall, our study demonstrates that by varying the amount of cross-linking agent, the cross-linked structure of the NSs matrix can be controlled effectively. As PMDA βCD-NSs have emerged over the years…

Selective laser sintering (SLS) is a powder bed fusion technology that uses a laser source to melt selected regions of a polymer powder bed based on 3D model data. Components with complex geometry are then obtained using a layer-by-layer strategy. This additive manufacturing technology is a very complex process in which various multiphysical phenomena and different mechanisms occur and greatly influence both the quality and performance of printed parts. This review describes the physical phenomena involved in the SLS process such as powder spreading, the interaction between laser beam and powder bed, polymer melting, coalescence of fused powder and its densification, and polymer crystallization. Moreover, the main characterization approaches that can be useful to investigate the starting material properties are reported and discussed.

This review was focused on expressing the effects of base liquid, temperature, possible surfactant, concentration and characteristics of nanoparticles including size, shape and material on thermal conductivity and viscosity of nanofluids. An increase in nanoparticle concentration can lead to an increase in thermal conductivity and viscosity and an increase in nanoparticle size, can increase or decrease thermal conductivity, while an increase in nanoparticle size decreases the viscosity of the nanofluid. The addition of surfactants at low concentrations can increase thermal conductivity, but at high concentrations, surfactants help to reduce thermal conductivity of the nanofluid. The addition of surfactants can decrease the nanofluid viscosity. Increasing the temperature, increased the thermal conductivity of a nanofluid, while decreasing its viscosity. Additionally, the effects of material of nanoparticles on the thermal conductivity and viscosity of a nanofluid need further investigations. In the case of hybrid nanofluids, it was observed that nanofluids with two different…

Various scenarios of end-of-life management of wind turbine blades are reviewed. "Reactive" strategies, designed to deal with already available, ageing turbines, installed in the 2000s, are discussed, among them, maintenance and repair, reuse, refurbishment and recycling. The main results and challenges of "pro-active strategies", designed to ensure recyclability of new generations of wind turbines, are discussed. Among the main directions, the wind turbine blades with thermoplastic and recyclable thermoset composite matrices, as well as wood, bamboo and natural fiber-based composites were reviewed. It is argued that repair and reuse of wind turbine blades, and extension of the blade life has currently a number of advantages over other approaches. While new recyclable materials have been tested in laboratories, or in some cases on small or medium blades, there are remaining technological challenges for their utilization in large wind turbine blades.

Nowadays, the rapid development and demand of high-performance, lightweight, low cost, portable/wearable electronic devices in electrical vehicles, aerospace, medical systems, etc., strongly motivates researchers towards advanced electrochemical energy storage (EES) devices and technologies. The electrolyte is also one of the most significant components of EES devices, such as batteries and supercapacitors. In addition to rapid ion transport and the stable electrochemical performance of electrolytes, great efforts are required to overcome safety issues due to flammability, leakage and thermal instability. A lot of research has already been completed on solid polymer electrolytes, but they are still lagging for practical application. Over the past few decades, ionic liquids (ILs) as electrolytes have been of considerable interest in Li-ion batteries and supercapacitor applications and could be an important way to make breakthroughs for the next-generation EES systems. The high ionic conductivity, low melting point (lower than 100 °C), wide electrochemical potential window (up to 5–6…

The aim of this review article is to present various material groups, including ceramics, composites and hybrid materials, currently utilized in the field of CAD/CAM. The described technology is amongst the most important in modern prosthetics. Materials that are applicable in this technique are constantly tested, evaluated and improved. Nowadays, research on dental materials is carried out in order to meet the increasing demand on highly aesthetic and functional indirect restorations. Recent studies present the long-term clinical success of restorations made with the help of both ceramic and composite materials in the CAD/CAM method. However, new materials are developed and introduced that do not have long-term in vivo observations. We can outline a monolithic polymer-infiltrated ceramic network and zirconia teeth support that show promising results to date but require further assessment. The materials will be compared with regard to their mechanical and clinical properties, purpose, advantages and limitations.

Although ultra high-performance concrete (UHPC) has great performance in strength and durability, it has a disadvantage in the environmental aspect; it contains a large amount of cement that is responsible for a high amount of CO2 emissions from UHPC. Supplementary cementitious materials (SCMs), industrial by-products or naturally occurring materials can help relieve the environmental burden by reducing the amount of cement in UHPC. This paper reviews the effect of SCMs on the properties of UHPC in the aspects of material properties and environmental impacts. It was found that various kinds of SCMs have been used in UHPC in the literature and they can be classified as slag, fly ash, limestone powder, metakaolin, and others. The effects of each SCM are discussed mainly on the early age compressive strength, the late age compressive strength, the workability, and the shrinkage of UHPC. It can be concluded that various forms of SCMs were successfully applied to UHPC possessing the material requirement of UHPC such as compressive strength. Finally, the analysis on the environmental…

Three-Dimensional mesoporous TiO2 scaffolds of anatase phase possess inherent eximious optical behavior that are beneficial in designing photoelectrodes for solar energy conversion applications. However, substantial efforts have been devoted in maximizing the UV and/or visible light absorption efficiency, and suppressing the annihilation of photogenerated charged species in pristine mesoporous TiO2 structure for improved solar illumination conversion efficiencies. This study provides the fundamental insights into Mxene functionalized mesoporous TiO2 as photoelectrode for the first time. This novel combination of Mxene functionalized TiO2 electrodes with and without TiCl4 treatments have been successfully optimized to intensify the process of photon absorption, charge segregation and photocurrent, resulting in superior photoelectrode performance. The photocurrent measurements of prepared photoelectrodes are significantly enhanced upon increased contents of Mxene due to improved absorption efficiency within the visible region as verified by UV–Vis absorption spectroscopy. Moreover, as…

The interactions between dislocations (dislocations and deformation twins) and boundaries (grain boundaries, twin boundaries and phase interfaces) during deformation at ambient temperatures are reviewed with focuses on interaction behaviors, boundary resistances and energies during the interactions, transmission mechanisms, grain size effects and other primary influencing factors. The structure of boundaries, interactions between dislocations and boundaries in coarse-grained, ultrafine-grained and nano-grained metals during deformation at ambient temperatures are summarized, and the advantages and drawbacks of different in-situ techniques are briefly discussed based on experimental and simulation results. The latest studies as well as fundamental concepts are presented with the aim that this paper can serve as a reference in the interactions between dislocations and boundaries during deformation.

The use of waste products in the production of asphalt binders and asphalt mixtures has become widespread due to economic and environmental benefits. In particular, the use of recycled waste plastic in asphalt binders and mixtures is gaining more attention. This review presents analyses and comparisons of various forms of waste plastic used in asphalt modification, and approaches to incorporating waste plastic into asphalt mixtures, both for single and composite modifications. It focuses on the properties of waste plastics, asphalt binders, and asphalt mixtures. Overall, the incorporation of plastic waste into asphalt mixtures can significantly improve high-temperature performance and has potential economic and environmental benefits. The performance of modified asphalt is highly dependent on multiple factors, such as waste sources, waste plastic dosages, blending conditions, and the pretreatment methods for waste plastic. There are different ways to apply waste plastics to blend into a mixture. In addition, this paper discusses the current challenges for waste plastic-modified…

A clean energy revolution is occurring across the world. As iron and steelmaking have a tremendous impact on the amount of CO2 emissions, there is an increasing attraction towards improving the green footprint of iron and steel production. Among reducing agents, hydrogen has shown a great potential to be replaced with fossil fuels and to decarbonize the steelmaking processes. Although hydrogen is in great supply on earth, extracting pure H2 from its compound is costly. Therefore, it is crucial to calculate the partial pressure of H2 with the aid of reduction reaction kinetics to limit the costs. This review summarizes the studies of critical parameters to determine the kinetics of reduction. The variables considered were temperature, iron ore type (magnetite, hematite, goethite), H2/CO ratio, porosity, flow rate, the concentration of diluent (He, Ar, N2), gas utility, annealing before reduction, and pressure. In fact, increasing temperature, H2/CO ratio, hydrogen flow rate and hematite percentage in feed leads to a higher reduction rate. In addition, the controlling kinetics models…

The inductively coupled plasma reactive ion etching (ICP-RIE) is a selective dry etching method used in fabrication technology of various semiconductor devices. The etching is used to form non-planar microstructures—trenches or mesa structures, and tilted sidewalls with a controlled angle. The ICP-RIE method combining a high finishing accuracy and reproducibility is excellent for etching hard materials, such as SiC, GaN or diamond. The paper presents a review of silicon carbide etching—principles of the ICP-RIE method, the results of SiC etching and undesired phenomena of the ICP-RIE process are presented. The article includes SEM photos and experimental results obtained from different ICP-RIE processes. The influence of O2 addition to the SF6 plasma as well as the change of both RIE and ICP power on the etching rate of the Cr mask used in processes and on the selectivity of SiC/Cr etching are reported for the first time. SiC is an attractive semiconductor with many excellent properties, that can bring huge potential benefits thorough advances in submicron semiconductor processing…

Composite materials are a combination of two or more types of materials used to enhance the mechanical and structural properties of engineering products. When fibers are mixed in the polymeric matrix, the composite material is known as fiber-reinforced polymer (FRP). FRP materials are widely used in structural applications related to defense, automotive, aerospace, and sports-based industries. These materials are used in producing lightweight components with high tensile strength and rigidity. The fiber component in fiber-reinforced polymers provides the desired strength-to-weight ratio; however, the polymer portion costs less, and the process of making the matrix is quite straightforward. There is a high demand in industrial sectors, such as defense and military, aerospace, automotive, biomedical and sports, to manufacture these fiber-reinforced polymers using 3D printing and additive manufacturing technologies. FRP composites are used in diversified applications such as military vehicles, shelters, war fighting safety equipment, fighter aircrafts, naval ships, and submarine…

The urbanization process contributes to the growth of solid waste generation and causes an increase in environmental impacts and failures in the management of solid waste. The number of dumps is a concern due to the limited implementation and safe disposal of this waste. The interest in sustainable techniques has been growing in relation to waste management, which is largely absorbed by the civil construction sector. This work aimed to review plastic waste, especially polyethylene terephthalate (PET), that can be incorporated with construction materials, such as concrete, mortars, asphalt mixtures, and paving. The use of life-cycle assessment (LCA) is related, as a tool that allows the sustainability of products and processes to be enhanced in the long term. After analyzing the recent literature, it was identified that studies related to plastic wastes in construction materials concentrate sustainability around the alternative destination of waste. Since the plastic waste from different production chains are obtained, it was possible to affirm the need for a broader assessment, such…

Polystyrene (PS) is one of the main polymer types of plastic wastes and is known to be resistant to biodegradation, resulting in PS waste persistence in the environment. Although previous studies have reported that some microorganisms can degrade PS, enzymes and mechanisms of microorganism PS biodegradation are still unknown. In this study, we summarized microbial species that have been identified to degrade PS. By screening the available genome information of microorganisms that have been reported to degrade PS for enzymes with functional potential to depolymerize PS, we predicted target PS-degrading enzymes. We found that cytochrome P4500s, alkane hydroxylases and monooxygenases ranked as the top potential enzyme classes that can degrade PS since they can break C-C bonds. Ring-hydroxylating dioxygenases may be able to break the side-chain of PS and oxidize the aromatic ring compounds generated from the decomposition of PS. These target enzymes were distributed in Proteobacteria, Actinobacteria, Bacteroidetes, and Firmicutes, suggesting a broad potential for PS biodegradation in…

The latest developments in solid propellants and their components are summarized. Particular attention is given to emerging energetic binders and novel, 'green' oxidizing agents and their use in propellant formulations. A brief overview of the latest reports on fuel additives is included. Finally, a summary of the state of the art and challenges in its development are speculated on.

Since their discovery, magnetic nanoparticles (MNPs) have become materials with great potential, especially considering the applications of biomedical sciences. A series of works on the preparation, characterization, and application of MNPs has shown that the biological activity of such materials depends on their size, shape, core, and shell nature. Some of the most commonly used MNPs are those based on a magnetite core. On the other hand, synthetic biopolymers are used as a protective surface coating for these nanoparticles. This review describes the advances in the field of polymer-coated MNPs for protein immobilization over the past decade. General methods of MNP preparation and protein immobilization are presented. The most extensive section of this article discusses the latest work on the use of polymer-coated MNPs for the physical and chemical immobilization of three types of proteins: enzymes, antibodies, and serum proteins. Where possible, the effectiveness of the immobilization and the activity and use of the immobilized protein are reported. Finally, the information…

Development of sustainable concrete as an alternative to conventional concrete helps in reducing carbon dioxide footprint associated with the use of cement and disposal of waste materials in landfill. One way to achieve that is the use of fly ash (FA) as an alternative to ordinary Portland cement (OPC) because FA is a pozzolanic material and has a high amount of alumina and silica content. Because of its excellent mechanical properties, several studies have been conducted to investigate the use of alkali-activated FA-based concrete as an alternative to conventional concrete. FA, as an industrial by-product, occupies land, thereby causing environmental pollution and health problems. FA-based concrete has numerous advantages, such as it has early strength gaining, it uses low natural resources, and it can be configurated into different structural elements. This study initially presents a review of the classifications, sources, chemical composition, curing regimes and clean production of FA. Then, physical, fresh, and mechanical properties of FA-based concretes are studied. This review…

A literature review comprising 163 publications published over a period of 26 years from 1992 to 2018 is presented in this paper. This review discusses the generation and recycling of construction and demolition waste (CDW) as well as its main uses as raw materials for the construction engineering sector. This review pays attention to the use of CDW aggregates for sand, pavements/roads, bricks, ceramics, cementitious materials, and concrete productions, as well its uses as eco-friendly materials for water decontamination. The physical-chemical and mechanical characteristics of recycled aggregates play an important role in their correctly chosen applications. The results found in this literature survey allow us to conclude that recycled aggregates from CDW can be successfully used to produce construction materials with quality comparable to those produced with natural aggregates. We concluded that the use of CDWs as raw materials for manufacturing new construction materials is technically feasible, economical, and constitutes an environmentally friendly approach for a future…

Carbon is one of the most abundant elements on Earth. In addition to the well-known crystallographic modifications such as graphite and diamond, other allotropic carbon modifications such as graphene-based nanomaterials and carbon nanotubes have recently come to the fore. These carbon nanomaterials can be designed to help deliver or target drugs more efficiently and to innovate therapeutic approaches, especially for cancer treatment, but also for the development of new diagnostic agents for malignancies and are expected to help combine molecular imaging for diagnosis with therapies. This paper summarizes the latest designed drug delivery nanosystems based on graphene, graphene quantum dots, graphene oxide, reduced graphene oxide and carbon nanotubes, mainly for anticancer therapy.

We present a simple and robust implementation of the phase field fracture method in Abaqus. Unlike previous works, only a user material (UMAT) subroutine is used. This is achieved by exploiting the analogy between the phase field balance equation and heat transfer, which avoids the need for a user element mesh and enables taking advantage of Abaqus' in-built features. A unified theoretical framework and its implementation are presented, suitable for any arbitrary choice of crack density function and fracture driving force. Specifically, the framework is exemplified with the so-called AT1, AT2 and phase field-cohesive zone models (PF-CZM). Both staggered and monolithic solution schemes are handled. We demonstrate the potential and robustness of this new implementation by addressing several paradigmatic 2D and 3D boundary value problems. The numerical examples show how the current implementation can be used to reproduce numerical and experimental results from the literature, and efficiently capture advanced features such as complex crack trajectories, crack nucleation from arbitrary…

Processing of aluminum alloys by wire arc additive manufacturing (WAAM) gained significant attention from industry and academia in the last decade. With the possibility to create large and relatively complex parts at low investment and operational expenses, WAAM is well-suited for implementation in a range of industries. The process nature involves fusion melting of a feedstock wire by an electric arc where metal droplets are strategically deposited in a layer-by-layer fashion to create the final shape. The inherent fusion and solidification characteristics in WAAM are governing several aspects of the final material, herein process-related defects such as porosity and cracking, microstructure, properties, and performance. Coupled to all mentioned aspects is the alloy composition, which at present is highly restricted for WAAM of aluminum but received considerable attention in later years. This review article describes common quality issues related to WAAM of aluminum, i.e., porosity, residual stresses, and cracking. Measures to combat these challenges are further outlined, with…

In the present study, pomegranate peel extract was used as a reinforcing agent in developing chitosan-based edible film. Different concentrations (0.2 g/mL, 0.4 g/mL, 0.6 g/mL, 0.8 g/mL, and 1.0 g/mL) of pomegranate peel extract were incorporated in chitosan-based edible film. A neat chitosan film was used as a control. This work covers the effect of pomegranate peel extract on the physical, biological, mechanical, thermal, and barrier properties of enriched chitosan-based edible film. The results showed that the thickness (0.142–0.159 mm), tensile strength (32.45–35.23 MPa), moisture (11.23–15.28%), opacity (0.039–0.061%), water (1.32–1.60 g·mm/m2), gas barrier properties (93.81–103.45 meq/kg), phenolic content (5.75–32.41 mg/g), and antioxidant activity (23.13–76.54%) of the films increased with increasing volume fraction of pomegranate peel extract. A higher concentration of incorporated pomegranate peel extracts significantly (p < 0.05) reduced the thermal stability of the film, along with its transparency, solubility, swelling, and color. This work revealed that the…

The term "critical raw materials" (CRMs) refers to various metals and nonmetals that are crucial to Europe's economic progress. Modern technologies enabling effective use and recyclability of CRMs are in critical demand for the EU industries. The use of CRMs, especially in the fields of biomedicine, aerospace, electric vehicles, and energy applications, is almost irreplaceable. Additive manufacturing (also referred to as 3D printing) is one of the key enabling technologies in the field of manufacturing which underpins the Fourth Industrial Revolution. 3D printing not only suppresses waste but also provides an efficient buy-to-fly ratio and possesses the potential to entirely change supply and distribution chains, significantly reducing costs and revolutionizing all logistics. This review provides comprehensive new insights into CRM-containing materials processed by modern additive manufacturing techniques and outlines the potential for increasing the efficiency of CRMs utilization and reducing the dependence on CRMs through wider industrial incorporation of AM and specifics of…

Fluorescent carbon dots (CDs) synthesized by pulsed laser ablation in liquid (PLAL) are still interesting materials due to their possible applications. However, unlike CDs produced by the hydrothermal method, CDs produced the synthesis products by the PLAL method were never separated by dialysis, which differentiates the synthesis products and allows the identification of the main source of fluorescence. In this work, the synthesis of fluorescent carbon dots (CDs) was performed by nanosecond laser ablation of a graphite target immersed in polyethyleneimine (PEI) and ethylenediamine (EDA), and the synthesis products were separated by dialysis. The results of optical measurements showed that the main source of luminescence of the obtained nanostructures are fluorescent particles or quasi-molecular fluorophores created in the ablation process. In the case of ablation in PEI, most of the produced molecular fluorophores are associated with carbogenic nanostructures, while in the case of EDA, free fluorescent molecules dominate.

Silica fume (SF) is a mineral additive that is widely used in the construction industry when producing sustainable concrete. The integration of SF in concrete as a partial replacement for cement has several evident benefits, including reduced CO2 emissions, cost-effective concrete, increased durability, and mechanical qualities. As environmental issues continue to grow, the development of predictive machine learning models is critical. Thus, this study aims to create modelling tools for estimating the compressive and cracking tensile strengths of silica fume concrete. Multilayer perceptron neural networks (MLPNN), adaptive neural fuzzy detection systems (ANFIS), and genetic programming are all used (GEP). From accessible literature data, a broad and accurate database of 283 compressive strengths and 149 split tensile strengths was created. The six most significant input parameters were cement, fine aggregate, coarse aggregate, water, superplasticizer, and silica fume. Different statistical measures were used to evaluate models, including mean absolute error, root mean square error,…

The concrete industry has long been adding discrete fibers to cementitious materials to compensate for their (relatively) low tensile strengths and control possible cracks. Extensive past studies have identified effective strategies to mix and utilize the discrete fibers, but as the fiber material properties advance, so do the properties of the cementitious composites made with them. Thus, it is critical to have a state-of-the-art understanding of not only the effects of individual fiber types on various properties of concrete, but also how those properties are influenced by changing the fiber type. For this purpose, the current study provides a detailed review of the relevant literature pertaining to different fiber types considered for fiber-reinforced concrete (FRC) applications with a focus on their capabilities, limitations, common uses, and most recent advances. To achieve this goal, the main fiber properties that are influential on the characteristics of cementitious composites in the fresh and hardened states are first investigated. The study is then extended to the…

Graphite is used as a state-of-the-art anode in commercial lithium-ion batteries (LIBs) due to its highly reversible lithium-ion storage capability and low electrode potential. However, graphite anodes exhibit sluggish diffusion kinetics for lithium-ion intercalation/deintercalation, thus limiting the rate capability of commercial LIBs. In order to determine the lithium-ion diffusion coefficient of commercial graphite anodes, we employed a galvanostatic intermittent titration technique (GITT) to quantify the quasi-equilibrium open circuit potential and diffusion coefficient as a function of lithium-ion concentration and potential for a commercial graphite electrode. Three plateaus are observed in the quasi-equilibrium open circuit potential curves, which are indicative of a mixed phase upon lithium-ion intercalation/deintercalation. The obtained diffusion coefficients tend to increase with increasing lithium concentration and exhibit an insignificant difference between charge and discharge conditions. This study reveals that the diffusion coefficient of graphite obtained with the…

Lithium-ion batteries (LiBs) are seen as a viable option to meet the rising demand for energy storage. To meet this requirement, substantial research is being accomplished in battery materials as well as operational safety. LiBs are delicate and may fail if not handled properly. The failure modes and mechanisms for any system can be derived using different methodologies like failure mode effects analysis (FMEA) and failure mode methods effects analysis (FMMEA). FMMEA is used in this paper as it helps to identify the reliability of a system at the component level focusing on the physics causing the observed failures and should thus be superior to the more data-driven FMEA approach. Mitigation strategies in LiBs to overcome the failure modes can be categorized as intrinsic safety, additional protection devices, and fire inhibition and ventilation. Intrinsic safety involves modifications of materials in anode, cathode, and electrolyte. Additives added to the electrolyte enhance the properties assisting in the improvement of solid-electrolyte interphase and stability. Protection devices…

Currently, the production of one ton of ordinary Portland cement (OPC) releases considerable amounts of CO2 into the atmosphere. As the need and demand for this material grows exponentially, it has become a challenge to increase its production at a time when climate-related problems represent a major global concern. The two main CO2 contributors in this process are fossil fuel combustion to heat the rotary kiln and the chemical reaction associated with the calcination process, in the production of the clinker, the main component of OPC. The current paper presents a critical review of the existent alternative clinker technologies (ACTs) that are under an investigation trial phase or under restricted use for niche applications and that lead to reduced emissions of CO2. Also, the possibility of transition of clinker production from traditional rotary kilns based on fuel combustion processes to electrification is discussed, since this may lead to the partial or even complete elimination of the CO2 combustion-related emissions, arising from the heating of the clinker kiln.

Today, the scientific community is facing crucial challenges in delivering a healthier world for future generations. Among these, the quest for circular and sustainable approaches for plastic recycling is one of the most demanding for several reasons. Indeed, the massive use of plastic materials over the last century has generated large amounts of long-lasting waste, which, for much time, has not been object of adequate recovery and disposal politics. Most of this waste is generated by packaging materials. Nevertheless, in the last decade, a new trend imposed by environmental concerns brought this topic under the magnifying glass, as testified by the increasing number of related publications. Several methods have been proposed for the recycling of polymeric plastic materials based on chemical or mechanical methods. A panorama of the most promising studies related to the recycling of polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), and polystyrene (PS) is given within this review.

In recent years, many researchers have begun to shift their focus onto the synthesis of nanomaterials as this field possesses immense potential that may provide incredible technological advances in the near future. The downside of conventional synthesis techniques, such as co-precipitation, sol-gel and hydrothermal methods, is that they necessitate the use of toxic chemicals, produce harmful by-products and require a considerable amount of energy; therefore, more sustainable fabrication routes are sought-after. Biological molecules have been previously utilized as precursors for nanoparticle synthesis, thus eliminating the negative factors involved in traditional methods. In addition, transition-metal nanoparticles possess a wide scope of applications due to their multiple oxidation states and large surface areas, thereby allowing for a higher reactivity when compared to their bulk counterpart and rendering them an interesting research topic. However, this field is still relatively unknown and unpredictable as the biosynthesis of these nanostructures from fungi, bacteria and plants…

One of the leading causes of morbidity and mortality worldwide is coronary artery disease, a condition characterized by the narrowing of the artery due to plaque deposits. The standard of care for treating this disease is the introduction of a stent at the lesion site. This life-saving tubular device ensures vessel support, keeping the blood-flow path open so that the cardiac muscle receives its vital nutrients and oxygen supply. Several generations of stents have been iteratively developed towards improving patient outcomes and diminishing adverse side effects following the implanting procedure. Moving from bare-metal stents to drug-eluting stents, and recently reaching bioresorbable stents, this research field is under continuous development. To keep up with how stent technology has advanced in the past few decades, this paper reviews the evolution of these devices, focusing on how they can be further optimized towards creating an ideal vascular scaffold.

Current COVID-19 pandemic caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has put a spotlight on the spread of infectious diseases brought on by pathogenic airborne bacteria and viruses. In parallel with a relentless search for therapeutics and vaccines, considerable effort is being expended to develop ever more powerful technologies to restricting the spread of airborne microorganisms in indoor spaces through the minimization of health- and environment-related risks. In this context, UV-based and photocatalytic oxidation (PCO)-based technologies (i.e., the combined action of ultraviolet (UV) light and photocatalytic materials such as titanium dioxide (TiO2)) represent the most widely utilized approaches at present because they are cost-effective and ecofriendly. The virucidal and bactericidal effect relies on the synergy between the inherent ability of UV light to directly inactivate viral particles and bacteria through nucleic acid and protein damages, and the production of oxidative radicals generated through the irradiation of the TiO2 surface. In this…

Tissue engineering (TE) scaffolds have enormous significance for the possibility of regeneration of complex tissue structures or even whole organs. Three-dimensional (3D) printing techniques allow fabricating TE scaffolds, having an extremely complex structure, in a repeatable and precise manner. Moreover, they enable the easy application of computer-assisted methods to TE scaffold design. The latest additive manufacturing techniques open up opportunities not otherwise available. This study aimed to summarize the state-of-art field of 3D printing techniques in applications for tissue engineering with a focus on the latest advancements. The following topics are discussed: systematics of the available 3D printing techniques applied for TE scaffold fabrication; overview of 3D printable biomaterials and advancements in 3D-printing-assisted tissue engineering.

Laser processing with ultra-short double pulses has gained attraction since the beginning of the 2000s. In the last decade, pulse bursts consisting of multiple pulses with a delay of several 10 ns and less found their way into the area of micromachining of metals, opening up completely new process regimes and allowing an increase in the structuring rates and surface quality of machined samples. Several physical effects such as shielding or re-deposition of material have led to a new understanding of the related machining strategies and processing regimes. Results of both experimental and numerical investigations are placed into context for different time scales during laser processing. This review is dedicated to the fundamental physical phenomena taking place during burst processing and their respective effects on machining results of metals in the ultra-short pulse regime for delays ranging from several 100 fs to several microseconds. Furthermore, technical applications based on these effects are reviewed.

Nowadays, people over the world face severe water scarcity despite the presence of several water sources. Adsorption is considered as the most efficient technique for the treatment of water containing biological, organic, and inorganic contaminants. For this purpose, materials from various origins (clay minerals, modified clays, zeolites, activated carbon, polymeric resins, etc.) have been considered as adsorbent for contaminants. Despite their cheapness and valuable properties, the use of clay minerals as adsorbent for wastewater treatment is limited due to many factors (low surface area, regeneration, and recovery limit, etc.). However, clay mineral can be used to enhance the performance of polymeric materials. The combination of clay minerals and polymers produces clay-polymers nanocomposites (CPNs) with advanced properties useful for pollutants removal. CPNs received a lot of attention for their efficient removal rate of various organic and inorganic contaminants via flocculation and adsorption ability. Three main classes of CPNs were developed (exfoliated nanocomposites (NCs),…

The aim of this work was to investigate the effect of two post-curing methods on the mechanical properties of a 3D-printed denture base material. Additionally, to compare the mechanical properties of that 3D-printed material with those of conventional autopolymerizing and a heat-cured denture base material. A resin for 3D-printing denture base (Imprimo®), a heat-polymerizing acrylic resin (Paladon® 65), and an autopolymerizing acrylic resin (Palapress®) were investigated. Flexural strength, elastic modulus, fracture toughness, work of fracture, water sorption, and water solubility were evaluated. The 3D-printed test specimens were post-cured using two different units (Imprimo Cure® and Form Cure®). The tests were carried out after both dry and 30 days water storage. Data were collected and statistically analyzed. Resin type had a significant effect on the flexural strength, elastic modulus, fracture toughness, and work of fracture (p < 0.001). The flexural strength and elastic modulus for the heat-cured polymer were significantly the highest among all investigated groups regardless…

Research on contamination of groundwater and drinking water is of major importance. Due to the rapid and significant progress in the last decade in nanotechnology and its potential applications to water purification, such as adsorption of heavy metal ion from contaminated water, a wide number of articles have been published. An evaluating frame of the main findings of recent research on heavy metal removal using magnetic nanoparticles, with emphasis on water quality and method applicability, is presented. A large number of articles have been studied with a focus on the synthesis and characterization procedures for bare and modified magnetic nanoparticles as well as on their adsorption capacity and the corresponding desorption process of the methods are presented. The present review analysis shows that the experimental procedures demonstrate high adsorption capacity for pollutants from aquatic solutions. Moreover, reuse of the employed nanoparticles up to five times leads to an efficiency up to 90%. We must mention also that in some rare occasions, nanoparticles have been reused up…

The rapid increase in the application of carbon fiber reinforced polymer (CFRP) composite materials represents a challenge to waste recycling. The circular economy approach coupled with the possibility of recovering carbon fibers from CFRP waste with similar properties to virgin carbon fibers at a much lower cost and with lower energy consumption motivate the study of CFRP recycling. Mechanical recycling methods allow the obtention of chopped composite materials, while both thermal and chemical recycling methods aim towards recovering carbon fibers. This review examines the three main recycling methods, their processes, and particularities, as well as the reuse of recycled carbon fibers in the manufacture of new composite materials.

Mechanical properties and data analysis for the prediction of different mechanical properties of geopolymer concrete (GPC) were investigated. A relatively large amount of test data from 126 past works was collected, analyzed, and correlation between different mechanical properties and compressive strength was investigated. Equations were proposed for the properties of splitting tensile strength, flexural strength, modulus of elasticity, Poisson's ratio, and strain corresponding to peak compressive strength. The proposed equations were found accurate and can be used to prepare a state-of-art report on GPC. Based on data analysis, it was found that there is a chance to apply some past proposed equations for predicting different mechanical properties. CEB-FIP equations for the prediction of splitting tensile strength and strain corresponding to peak compressive stress were found to be accurate, while ACI 318 equations for splitting tensile and elastic modulus overestimates test data for GPC of low compressive strength.

This review article proposes the identification and basic concepts of materials that might be used for the production of high-performance concrete (HPC) and ultra-high-performance concrete (UHPC). Although other reviews have addressed this topic, the present work differs by presenting relevant aspects on possible materials applied in the production of HPC and UHPC. The main innovation of this review article is to identify the perspectives for new materials that can be considered in the production of novel special concretes. After consulting different bibliographic databases, some information related to ordinary Portland cement (OPC), mineral additions, aggregates, and chemical additives used for the production of HPC and UHPC were highlighted. Relevant information on the application of synthetic and natural fibers is also highlighted in association with a cement matrix of HPC and UHPC, forming composites with properties superior to conventional concrete used in civil construction. The article also presents some relevant characteristics for the application of HPC and UHPC produced…

The huge plastic production and plastic pollution are considered important global issues due to environmental aspects. One practical and efficient way to address them is to replace fossil-based plastics with natural-based materials, such as cellulose. The applications of different cellulose products have recently received increasing attention because of their desirable properties, such as biodegradability and sustainability. In this regard, the current study initially reviews cellulose products' properties in three categories, including biopolymers based on the cellulose-derived monomer, cellulose fibers and their derivatives, and nanocellulose. The available life cycle assessments (LCA) for cellulose were comprehensively reviewed and classified at all the stages, including extraction of cellulose in various forms, manufacturing, usage, and disposal. Finally, due to the development of low-carbon materials in recent years and the importance of greenhouse gases (GHG) emissions, the proposed solutions to make cellulose a low carbon material were made. The optimization of the cellulose…

The selection of biomaterials for bearing in total hip arthroplasty is very important to avoid various risks of primary postoperative failure for patients. The current investigation attempts to analyze the Tresca stress of metal-on-metal bearings with three different materials, namely, cobalt chromium molybdenum (CoCrMo), stainless steel 316L (SS 316L), and titanium alloy (Ti6Al4V). We used computational simulations using a 2D axisymmetric finite element model to predict Tresca stresses under physiological conditions of the human hip joint during normal walking. The simulation results show that Ti6Al4V-on-Ti6Al4V has the best performance to reduce Tresca stress by 45.76% and 39.15%, respectively, compared to CoCrMo-on-CoCrMo and SS 316L-on-SS 316L.

This paper reviews the current trends in replacing commonly used plasticizers in poly(vinyl chloride), PVC, formulations by new compounds with reduced migration, leading to the enhancement in mechanical properties and better plasticizing efficiency. Novel plasticizers have been divided into three groups depending on the replacement strategy, i.e., total replacement, partial replacement, and internal plasticizers. Chemical and physical properties of PVC formulations containing a wide range of plasticizers have been compared, allowing observance of the improvements in polymer performance in comparison to PVC plasticized with conventionally applied bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, bis(2-ethylhexyl) terephthalate and di-n-octyl terephthalate. Among a variety of newly developed plasticizers, we have indicated those presenting excellent migration resistance and advantageous mechanical properties, as well as those derived from natural sources. A separate chapter has been dedicated to the description of a synergistic effect of a mixture of two plasticizers, primary and…

This study aims to obtain the relationship between density and compressive strength of foamed concrete. Foamed concrete is a preferred building material due to the low density of its concrete. In foamed concrete, the compressive strength reduces with decreasing density. Generally, a denser foamed concrete produces higher compressive strength and lower volume of voids. In the present study, the tests were carried out in stages in order to investigate the effect of sand–cement ratio, water to cement ratio, foam dosage, and dilution ratio on workability, density, and compressive strength of the control foamed concrete specimen. Next, the test obtained the optimum content of processed spent bleaching earth (PSBE) as partial cement replacement in the foamed concrete. Based on the experimental results, the use of 1:1.5 cement to sand ratio for the mortar mix specified the best performance for density, workability, and 28-day compressive strength. Increasing the sand to cement ratio increased the density and compressive strength of the mortar specimen. In addition, in the production of…

Additive manufacturing enables innovative structural design for industrial applications, which allows the fabrication of lattice structures with enhanced mechanical properties, including a high strength-to-relative-density ratio. However, to commercialize lattice structures, it is necessary to define the designability of lattice geometries and characterize the associated mechanical responses, including the compressive strength. The objective of this study was to provide an optimized design process for lattice structures and develop a lattice structure characterization database that can be used to differentiate unit cell topologies and guide the unit cell selection for compression-dominated structures. Linear static finite element analysis (FEA), nonlinear FEA, and experimental tests were performed on 11 types of unit cell-based lattice structures with dimensions of 20 mm × 20 mm × 20 mm. Consequently, under the same relative density conditions, simple cubic, octahedron, truncated cube, and truncated octahedron-based lattice structures with a 3 × 3 × 3 array pattern showed the best…

At present, the world is at the peak of production of traditional fossil fuels. Much of the resources that humanity has been consuming (oil, coal, and natural gas) are coming to an end. The human being faces a future that must necessarily go through a paradigm shift, which includes a progressive movement towards increasingly less polluting and energetically viable resources. In this sense, nanotechnology has a transcendental role in this change. For decades, new materials capable of being used in energy processes have been synthesized, which undoubtedly will be the cornerstone of the future development of the planet. In this review, we report on the current progress in the synthesis and use of one-dimensional (1D) nanostructured materials (specifically nanowires, nanofibers, nanotubes, and nanorods), with compositions based on oxides, nitrides, or metals, for applications related to energy. Due to its extraordinary surface-volume relationship, tunable thermal and transport properties, and its high surface area, these 1D nanostructures have become fundamental elements for the…

The casting and testing specimens for determining the mechanical properties of concrete is a time-consuming activity. This study employed supervised machine learning techniques, bagging, AdaBoost, gene expression programming, and decision tree to estimate the compressive strength of concrete containing supplementary cementitious materials (fly ash and blast furnace slag). The performance of the models was compared and assessed using the coefficient of determination (R2), mean absolute error, mean square error, and root mean square error. The performance of the model was further validated using the k-fold cross-validation approach. Compared to the other employed approaches, the bagging model was more effective in predicting results, with an R2 value of 0.92. A sensitivity analysis was also prepared to determine the level of contribution of each parameter utilized to run the models. The use of machine learning (ML) techniques to predict the mechanical properties of concrete will be beneficial to the field of civil engineering because it will save time, effort, and resources. The…

Thanks to the continuous development of light-curing resin composites it is now possible to print permanent single-tooth restorations. The purpose of this study was to compare resin composites for milling -Gandio Blocks (GR), Brilliant Crios (CR) and Enamic (EN) with resin composite for 3D printing—Varseo Smile Crown plus (VSC). Three-point bending was used to measure flexural strength (σf) and flexural modulus (Ef). The microhardness was measured using a Vickers method, while fractographic, microstructural, texture and fractal dimension (FD) analyses were performed using SEM, optical microscope and picture analysis methods. The values of σf ranged from 118.96 (±2.81) MPa for EN to 186.02 (±10.49) MPa for GR, and the values of Ef ranged from 4.37 (±0.8) GPa for VSC to 28.55 (±0.34) GPa for EN. HV01 ranged from 25.8 (±0.7) for VSC to 273.42 (±27.11) for EN. The filler content ranged from 19–24 vol. % for VSC to 70–80 vol. % for GR and EN. The observed fractures are typical for brittle materials. The correlation between FD of materials microstructure and Ef was observed. σf of the…

In this review, we describe the application of thermosensitive hydrogels composed of poloxamer in medicine, especially for oral cavities. Thermosensitive hydrogels remain fluid at room temperature; at body temperature, they become more viscous gels. In this manner, the gelling system can remain localized for considerable durations and control and prolong drug release. The chemical structure of the poloxamer triblock copolymer leads to an amphiphilic aqueous solution and an active surface. Moreover, the poloxamer can gel by forming micelles in an aqueous solution, depending on its critical micelle concentration and critical micelle temperature. Owing to its controlled-release effect, a thermosensitive gel based on poloxamer 407 (P407) is used to deliver drugs with different characteristics. As demonstrated in studies on poloxamer formulations, an increase in gelling viscosity decreases the drug release rate and gel dissolution time to the extent that it prolongs the drug's duration of action in disease treatment. This property is used for drug delivery and different therapeutic…

Abstract: For the production of geopolymer concrete (GPC), fly-ash (FA) like waste material has been effectively utilized by various researchers. In this paper, the soft computing techniques known as gene expression programming (GEP) are executed to deliver an empirical equation to estimate the compressive strength f_c^' of GPC made by employing FA. To build a model, a consistent, extensive and reliable data base is compiled through a detailed review of the published research. The compiled data set is comprised of 298 f_c^' experimental results. The utmost dominant parameters are counted as explanatory variables, in other words, the extra water added as percent FA (%E_W), the percentage of plasticizer (%P), the initial curing temperature (T), the age of the specimen (A), the curing duration (t), the fine aggregate to total aggregate ratio (F⁄A_G ), the percentage of total aggregate by volume ( 〖%A〗_G), the percent SiO2 solids to water ratio (% S/W) in sodium silicate (Na2SiO3) solution, the NaOH solution molarity (M), the activator or alkali to FA ratio (A_L⁄F_A ), the sodium oxide…

The scientific community has made great efforts in advancing magnetic hyperthermia for the last two decades after going through a sizeable research lapse from its establishment. All the progress made in various topics ranging from nanoparticle synthesis to biocompatibilization and in vivo testing have been seeking to push the forefront towards some new clinical trials. As many, they did not go at the expected pace. Today, fruitful international cooperation and the wisdom gain after a careful analysis of the lessons learned from seminal clinical trials allow us to have a future with better guarantees for a more definitive takeoff of this genuine nanotherapy against cancer. Deliberately giving prominence to a number of critical aspects, this opinion review offers a blend of state-of-the-art hints and glimpses into the future of the therapy, considering the expected evolution of science and technology behind magnetic hyperthermia.

The adsorption capacity of synthetic NaX zeolite for Pb2+, Cd2+, Cu2+ and Zn2+ in single and multi-component systems were investigated. The effects of electronegativity and hydration energy on the selective adsorption, as well as potential selective adsorption mechanism of the NaX zeolite for Pb2+, Cd2+, Cu2+ and Zn2+ were also discussed. The maximum adsorption capacity order of the heavy metals in the single system was Pb2+ > Cd2+ > Cu2+ > Zn2+, and this could be related to their hydration energy and electronegativity. The values of the separation factors (α) and affinity constant (KEL) in different binary systems indicated that Pb2+ was preferentially adsorbed, and Zn2+ presented the lowest affinity for NaX zeolite. The selective adsorption capacities of the metals were in the order, Pb2+ > Cd2+ ≈ Cu2+ > Zn2+. The trend for the selective adsorption of NaX zeolite in ternary and quaternary systems was consistent with that in the binary systems. Pb2+ and Cu2+ reduced the stability of the Si-O-Al bonds and the double six-membered rings in the NaX framework, due to the high…

Over the last two decades, calcium silicate-based materials have grown in popularity. As root canal sealers, these formulations have been extensively investigated and compared with conventional sealers, such as zinc oxide-eugenol and epoxy resin-based sealers, in in vitro studies that showed their promising properties, especially their biocompatibility, antimicrobial properties, and certain bioactivity. However, the consequence of their higher solubility is a matter of debate and still needs to be clarified, because it may affect their long-term sealing ability. Unlike conventional sealers, those sealers are hydraulic, and their setting is conditioned by the presence of humidity. Current evidence reveals that the properties of calcium silicate-based sealers vary depending on their formulation. To date, only a few short-term investigations addressed the clinical outcome of calcium silicate-based root canal sealers. Their use has been showed to be mainly based on practitioners' clinical habits rather than manufacturers' recommendations or available evidence. However, their particular…

Supplementary cementitious materials (SCMs) and chemical additives (CA) are incorporated to modify the properties of concrete. In this paper, SCMs such as fly ash (FA), ground granulated blast furnace slag (GGBS), silica fume (SF), rice husk ash (RHA), sugarcane bagasse ash (SBA), and tire-derived fuel ash (TDFA) admixed concretes are reviewed. FA (25–30%), GGBS (50–55%), RHA (15–20%), and SBA (15%) are safely used to replace Portland cement. FA requires activation, while GGBS has undergone in situ activation, with other alkalis present in it. The reactive silica in RHA and SBA readily reacts with free Ca(OH)2 in cement matrix, which produces the secondary C-S-H gel and gives strength to the concrete. SF addition involves both physical contribution and chemical action in concrete. TDFA contains 25–30% SiO2 and 30–35% CaO, and is considered a suitable secondary pozzolanic material. In this review, special emphasis is given to the various chemical additives and their role in protecting rebar from corrosion. Specialized concrete for novel applications, namely self-curing, self-healing,…

Structures located on the coast are subjected to the long-term influence of chloride ions, which cause the corrosion of steel reinforcements in concrete elements. This corrosion severely affects the performance of the elements and may shorten the lifespan of an entire structure. Even though experimental activities in laboratories might be a solution, they may also be problematic due to time and costs. Thus, the application of individual machine learning (ML) techniques has been investigated to predict surface chloride concentrations (Cc) in marine structures. For this purpose, the values of Cc in tidal, splash, and submerged zones were collected from an extensive literature survey and incorporated into the article. Gene expression programming (GEP), the decision tree (DT), and an artificial neural network (ANN) were used to predict the surface chloride concentrations, and the most accurate algorithm was then selected. The GEP model was the most accurate when compared to ANN and DT, which was confirmed by the high accuracy level of the K-fold cross-validation and linear correlation…

It has been established in literature that the addition of nanoparticles to lubricants at an optimum concentration results in a lower coefficient of friction compared to lubricants with no nanoparticle additives. This review paper shows a comparison of different lubricants based on the COF (coefficient of friction) with nanoadditives. The effect of the addition of nanoparticles on the friction coefficient was analyzed for both synthetic and biolubricants separately. The limitations associated with the use of nanoparticles are explained. The mechanisms responsible for a reduction in friction when nanoparticles are used as an additive are also discussed. Various nanoparticles that have been most widely used in recent years showed good performance within lubricants, including CuO (copper oxide), MoS2 (molybdenum disulfide), and TiO2 (titanium dioxide). The paper also indicates some research gaps that need to be addressed.

In the field of industrial wastewater treatment, membrane separation technology, as an emerging separation technology, compared with traditional separation technology such as precipitation, adsorption, and ion exchange, has advantages in separation efficiency, low energy consumption, low cost, simple operation, and no secondary pollution. The application has been expanding in recent years, but membrane fouling and other problems have seriously restricted the development of membrane technology. Natural cellulose is one of the most abundant resources in nature. In addition, nanocellulose has characteristics of high strength and specific surface area, surface activity groups, as well as being pollution-free and renewable, giving it a very wide development prospect in many fields, including membrane separation technology. This paper reviews the current status of nanocellulose filtration membrane, combs the widespread types of nanocellulose and its derivatives, and summarizes the current application of cellulose in membrane separation. In addition, for the purpose of nanocellulose…

During the past few years, researchers have focused their attention on developing innovative nanocomposite polymeric membranes with applications in water purification. Natural and synthetic polymers were considered, and it was proven that chitosan-based materials presented important features. This review presents an overview regarding diverse materials used in developing innovative chitosan-based nanocomposite polymeric membranes for water purification. The first part of the review presents a detailed introduction about chitosan, highlighting the fact that is a biocompatible, biodegradable, low-cost, nontoxic biopolymer, having unique structure and interesting properties, and also antibacterial and antioxidant activities, reasons for using it in water treatment applications. To use chitosan-based materials for developing nanocomposite polymeric membranes for wastewater purification applications must enhance their performance by using different materials. In the second part of the review, the performance's features will be presented as a consequence of adding different nanoparticles,…

Plastic waste reduction and recycling through circular use has been critical nowadays, since there is an increasing demand for the production of plastic components based on different polymeric matrices in various applications. The most commonly used recycling procedure, especially for thermoplastic materials, is based on thermomechanical process protocols that could significantly alter the polymers' macromolecular structure and physicochemical properties. The study at hand focuses on recycling of polyamide 12 (PA12) filament, through extrusion melting over multiple recycling courses, giving insight for its effect on the mechanical and thermal properties of Fused Filament Fabrication (FFF) manufactured specimens throughout the recycling courses. Three-dimensional (3D) FFF printed specimens were produced from virgin as well as recycled PA12 filament, while they have been experimentally tested further for their tensile, flexural, impact and micro-hardness mechanical properties. A thorough thermal and morphological analysis was also performed on all the 3D printed samples. The results…

Polyetheretherketone (PEEK) is an important high-performance thermoplastic. Its excellent strength, stiffness, toughness, fatigue resistance, biocompatibility, chemical stability and radiolucency have made PEEK attractive in dental and orthopedic applications. However, PEEK has an inherently hydrophobic and chemically inert surface, which has restricted its widespread use in clinical applications, especially in bonding with dental resin composites. Cutting edge research on novel methods to improve PEEK applications in dentistry, including oral implant, prosthodontics and orthodontics, is reviewed in this article. In addition, this article also discusses innovative surface modifications of PEEK, which are a focus area of active investigations. Furthermore, this article also discusses the necessary future studies and clinical trials for the use of PEEK in the human oral environment to investigate its feasibility and long-term performance.

Concrete is the most common building material; therefore, when designing structures, it is obligatory to consider all structural parameters and design characteristics such as acoustic properties. In particular, this is to ensure comfortable living conditions for people in residential premises, including acoustic comfort. Different types of concrete behave differently as a sound conductor; especially dense mixtures are superior sound reflectors, and light ones are sound absorbers. It is found that the level of sound reflection in modified concrete is highly dependent on the type of aggregates, size and distribution of pores, and changes in concrete mix design constituents. The sound absorption of acoustic insulation concrete (AIC) can be improved by forming open pores in concrete matrices by either using a porous aggregate or foam agent. To this end, this article reviews the noise and sound transmission in buildings, types of acoustic insulating materials, and the AIC properties. This literature study also provides a critical review on the type of concretes, the acoustic insulation…

The synthesis of nanoparticles by green approaches is gaining unique importance due to its low cost, biocompatibility, high productivity, and purity, and being environmentally friendly. Herein, biomass filtrate of Pseudomonas aeruginosa isolated from mangrove rhizosphere sediment was used for the biosynthesis of zinc oxide nanoparticles (ZnO-NPs). The bacterial isolate was identified based on morphological, physiological, and 16S rRNA. The bio-fabricated ZnO-NPs were characterized using color change, UV-visible spectroscopy, FT-IR, TEM, and XRD analyses. In the current study, spherical and crystalline nature ZnO-NPs were successfully formed at a maximum SPR (surface plasmon resonance) of 380 nm. The bioactivities of fabricated ZnO-NPs including antibacterial, anti-candida, and larvicidal efficacy were investigated. Data analysis showed that these bioactivities were concentration-dependent. The green-synthesized ZnO-NPs exhibited high efficacy against pathogenic Gram-positive bacteria (Staphylococcus aureus and Bacillus subtilis), Gram-negative bacteria (Escherichia coli and…

The use of biofuels offers advantages over existing fuels because they come from renewable sources, they are biodegradable, their storage and transport are safer, and their emissions into the atmosphere are lower. Biomass is one of the most promising sustainable energy sources with a wide variety of organic materials as raw material. Chemical, biochemical, and thermochemical methods have been proposed to obtain biofuels from raw materials from biomass. In recent years, a thermochemical method that has generated great interest is hydrothermal liquefaction. In this paper, a brief review of the main sources for liquid biofuels and the synthesis processes is presented, with special emphasis on the production of biofuels using hydrothermal liquefaction by using waste generated by human activity as raw material.

Carbon fiber-reinforced composites present an exciting combination of properties and offer clear advantages that make them a perfect replacement for a spread of materials. Consequently, in recent years, their production has dramatically increased as well as the quantity of waste materials. As future legislations are likely to prevent the use of landfills and incineration to dispose of composite waste, alternative solutions such as recycling are considered as one of the urgent problems to be settled. This study presents the leading technologies for recycling carbon fiber-reinforced composites, focusing on chemical recycling using sub- and supercritical fluids. These new reaction media have been demonstrated to be more manageable and efficient in recovering clean fibers with good mechanical properties. The conventional technologies of carbon fibers recycling have also been reviewed and described with both advantages and drawbacks.

Current discoveries as well as research findings on various types of carbon nanostructures have inspired research into their utilization in a number of fields. These carbon nanostructures offer uses in pharmacy, medicine and different therapies. One such unique carbon nanostructure includes carbon nanotubes (CNTs), which are one-dimensional allotropes of carbon nanostructure that can have a length-to-diameter ratio greater than 1,000,000. After their discovery, CNTs have drawn extensive research attention due to their excellent material properties. Their physical, chemical and electronic properties are excellent and their composites provide great possibilities for enormous nanometer applications. The current study provides a systematic review based on prior literature review and data gathered from various sources. The various research studies from many research labs and organizations were systematically retrieved, collected, compiled and written. The entire collection and compilation of this review concluded the use of CNT approaches and their efficacy and safety for the treatment…

Artificial intelligence and machine learning are employed in creating functions for the prediction of self-compacting concrete (SCC) strength based on input variables proportion as cement replacement. SCC incorporating waste material has been used in learning approaches. Artificial neural network (ANN) support vector machine (SVM) and gene expression programming (GEP) consisting of 300 datasets have been utilized in the model to foresee the mechanical property of SCC. Data used in modeling consist of several input parameters such as cement, water–binder ratio, coarse aggregate, fine aggregate, and fly ash (FA) in combination with the superplasticizer. The best predictive models were selected based on the coefficient of determination (R2) results and model validation. Empirical relation with mathematical expression has been proposed using ANN, SVM, and GEP. The efficiency of the models is assessed by permutation features importance, statistical analysis, and comparison between regression models. The results reveal that the proposed machine learning models achieved adamant accuracy…

This review provides a report on properties and recent research advances in the application of plant-derived colorants in food, cosmetics and textile materials. The following colorants are reviewed: Polyphenols (anthocyanins, flavonol-quercetin and curcumin), isoprenoids (iridoids, carotenoids and quinones), N-heterocyclic compounds (betalains and indigoids), melanins and tetrapyrroles with potential application in industry. Future aspects regarding applications of plant-derived colorants in the coloration of various materials are also discussed.

Starch films can be used as materials for food packaging purposes. The goal of this study is to compare how the starch origin influence the selected starch film properties. The films were made from various starches such as that from maize, potato, oat, rice, and tapioca using 50%w of glycerine as a plasticizer. The obtained starch-based films were made using the well-known casting method from a starch solution in water. The properties of the films that were evaluated were tensile strength, water vapour transition rate, moisture content, wettability, and their surface free energy. Surface free energy (SFE) and its polar and dispersive components were calculated using the Owens-Wendt-Rabel-Kaelbe approach. The values of SFE in the range of 51.64 to 70.81 mJ∙m−2 for the oat starch-based film and the maize starch-based film. The films revealed worse mechanical properties than those of conventional plastics for packaging purposes. The results indicated that the poorest tensile strength was exhibited by the starch-based films made from oat (0.36 MPa) and tapioca (0.78 MPa) and the…

The gamma radiation shielding ability for CaO-K2O-Na2O-P2O5 glasses were experimentally determined between 0.0595 and 1.41 MeV. The experimental MAC results were compared with theoretical results obtained from the XCOM software to test the accuracy of the experimental values. Additionally, the effect of increasing the P2O5 in the glass composition, or reducing the Na2O content, was evaluated at varying energies. For the fabricated glasses, the experimental data strongly agreed with the XCOM results. The effective atomic number (Zeff) of the fabricated glasses was also determined. The Zeff values start out at their maximum (12.41–12.55) at the lowest tested energy, 0.0595 MeV, and decrease to 10.69–10.80 at 0.245 MeV. As energy further increases, the Zeff values remain almost constant between 0.344 and 1.41 MeV. The mean free path (MFP) of the fabricated glasses is investigated and we found that the lowest MFP value occurs at the lowest tested energy, 0.0595 MeV, and lies within the range of 1.382–1.486 cm, while the greatest MFP can be found at the highest tested energy, 1.41 MeV,…